Recent development in the study of SN2 reactions at heteroatoms and ion pair systems

被引：15
|
作者：
Ren, Y [1 ]
Chu, SY
机构：
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
[2] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
来源：
JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY | 2006年 / 5卷 / 01期
关键词：
bimolecular nucleophilic substitution; heteroatoms; ion-pair; reaction mechanisms; quantum chemistry calculation;
D O I：
10.1142/S021963360600212X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Present review outlines the experimental and theoretical studies on the S(N)2 reactions at heteroatoms (N, O and S) and ion pair systems in recent years, especially introduce research carried out at our group in detail. The similarities and differences between S(N)2 at heteroatoms and at carbon are discussed. Some new structure-energy relationships were proposed. The accuracy of various theoretical schemes for calculating potential energy surfaces has been assessed.
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页码：121 / 140
页数：20
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