Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex

被引：47
作者：
Guo, Ying
Yang, Xiu-Long
Wei, Rong-Jia
Zheng, Lan-Sun
Tao, Jun [1 ]
机构：
[1] Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
INORGANIC CHEMISTRY | 2015年 / 54卷 / 16期
基金：
中国国家自然科学基金;
关键词：
LONG ALKYL CHAINS; MAGNETIC-PROPERTIES; CROSSOVER COMPOUNDS; COMPOUND; STATE; PRESSURE; EXCHANGE; BEHAVIOR; STIMULI;
D O I：
10.1021/acs.inorgchem.5b01344
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A mononuclear compound, [Co-II(pyterpy)(2)](PF6)(2)-2CH(3)OH [2; pyterpy = 4'-(4 ''' pyridy1)-2,2':6',2 ''-terpyridine], shows a phase-transitioncoupled, abrupt spin transition with a 9 K wide hysteresis that can transform to a spin-crossover compound, [Co-II(p-yterpy)(2)](PF6)(2).2CH(2)Cl(2)-CH3OH (3).
引用
收藏
页码：7670 / 7672
页数：3
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