Biphasic single-reactor process for dehydration of xylose and hydrogenation of produced furfural

被引：103

作者：

Ordomsky, V. V. ^{[1
]}

Schouten, J. C. ^{[1
]}

van der Schaaf, J. ^{[1
]}

Nijhuis, T. A. ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Lab Chem Reactor Engn, NL-5600 MB Eindhoven, Netherlands

来源：

APPLIED CATALYSIS A-GENERAL | 2013年 / 451卷

关键词：

Xylose dehydration; Furfural; Hydrogenation; Biphasic process; ION-EXCHANGE-RESIN; TETRAHYDROFURFURYL ALCOHOL; GLYCEROL HYDROGENOLYSIS; CATALYTIC-HYDROGENATION; PHASE HYDROGENATION; FURAN-DERIVATIVES; ACID CATALYSTS; BIOMASS; CYCLOPENTANONE; TRANSFORMATION;

D O I：

10.1016/j.apcata.2012.11.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The processes of xylose dehydration and the consecutive furfural hydrogenation have been combined in a single biphasic reactor. The dehydration was studied over Amberlyst-15 and the hydrogenation over a hydrophobic Ru/C catalyst. 1-Butanol, 2-methyltetrahydrofuran and cyclohexane were used as solvents in the process. The hydrogenation catalyst in the reactor was present in the organic phase and the dehydration catalyst in the aqueous phase. An increase of the hydrophobicity of the solvent in the order 1-butanol <2-methyltetrahydrofuran < cyclohexane suppressed the hydrogenation of xylose to xylitol due to a decrease of the xylose solubility, while forming furfural hydrogenation products. The main product is tetrahydrofurfuryl alcohol. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：6 / 13

页数：8

共 33 条

[1] The selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using heterogeneous catalysts
Alamillo, Ricardo
Tucker, Mark
Chia, Mei
Pagan-Torres, Yomaira
Dumesic, James
[J]. GREEN CHEMISTRY, 2012, 14 (05) : 1413 - 1419
[2] Production of Biofuels from Cellulose and Corn Stover Using Alkylphenol Solvents
Alonso, David Martin
Wettstein, Stephanie G.
Bond, Jesse Q.
Root, Thatcher W.
Dumesic, James A.
[J]. CHEMSUSCHEM, 2011, 4 (08) : 1078 - 1081
[3] KINETIC-STUDIES OF THE REACTIONS OF KETOSES AND ALDOSES IN WATER AT HIGH-TEMPERATURE .3. MECHANISM OF FORMATION OF 2-FURALDEHYDE FROM D-XYLOSE
ANTAL, MJ
LEESOMBOON, T
MOK, WS
RICHARDS, GN
[J]. CARBOHYDRATE RESEARCH, 1991, 217 : 71 - 85
[4] Aqueous-phase dehydration of xylose to furfural in the presence of MCM-22 and ITQ-2 solid acid catalysts
Antunes, Margarida M.
Lima, Sergio
Fernandes, Auguste
Pillinger, Martyn
Ribeiro, Maria F.
Valente, Anabela A.
[J]. APPLIED CATALYSIS A-GENERAL, 2012, 417 : 243 - 252
[5] Brown L. H., 1960, J CHEM ENG DATA, V5, P56
[6] Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides
Chheda, Juben N.
Roman-Leshkov, Yuriy
Dumesic, James A.
[J]. GREEN CHEMISTRY, 2007, 9 (04) : 342 - 350
[7] PYRIDINE SYNTHESIS FROM TETRAHYDROFURFURYL ALCOHOL OVER A PD/GAMMA-AL2O3 CATALYST .2. EFFECT OF SUPPORTS AND PALLADIUM LOADING
CHOI, JH
LEE, WY
[J]. APPLIED CATALYSIS A-GENERAL, 1993, 98 (01) : 21 - 31
[8] Chemical routes for the transformation of biomass into chemicals
Corma, Avelino
Iborra, Sara
Velty, Alexandra
[J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2411 - 2502
[9] Dehydration of xylose into furfural over micro-mesoporous sulfonic acid catalysts
Dias, AS
Pillinger, M
Valente, AA
[J]. JOURNAL OF CATALYSIS, 2005, 229 (02) : 414 - 423
[10] Determination of the relative leaching kinetics of Cu, Rh, Ru and Ir during the sulphuric acid pressure leaching of leach residue derived from Ni-Cu converter matte enriched in platinum group metals
Dorfling, C.
Akdogan, G.
Bradshaw, S. M.
Eksteen, J. J.
[J]. MINERALS ENGINEERING, 2011, 24 (06) : 583 - 589

← 1 2 3 4 →