Luminescent Tags on Fullerenes: Eu3+ Complexes with Pendant Fullerenes

被引：8
作者：
Fuchsbatter, Anita [1 ]
Troshina, Olesya A. [2 ]
Troshin, Pavel A. [2 ]
Koeppe, Robert [1 ]
Lyubovskaya, Rimma N. [2 ]
Sariciftci, Niyazi Serdar [1 ]
机构：
[1] Johannes Kepler Univ Linz, Linz Inst Organ Solar Cells, A-4040 Linz, Austria
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
来源：
ADVANCED FUNCTIONAL MATERIALS | 2008年 / 18卷 / 18期
关键词：
D O I：
10.1002/adfm.200800377
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel fullerene-containing Eu (III) complexes are obtained by mixing a fullerene derivative bearing chelating pyridinyl groups with an Eu (III) complex possessing three coordinated 4,4,4,-trifluoro-1-(2-naphtyl)-1,3-butanedione residues and two water molecules. One of the complexes designed is formed in water using a water-soluble fullerene derivative as a precursor material. We investigate the photophysical properties of this new type of highly soluble self-assembled fullerene-derivative Eu3+ coordination compounds. A strong emission line of the Eu3+ 4f-4f transition is recorded under excitation with UV irradiation. The behaviour of the complexes in organic matrices and water is studied as the first steps towards luminescence tagged fullerene derivatives for use in biomedicine and optoelectronics.
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收藏
页码：2808 / 2814
页数：7
相关论文
共 51 条
  • [21] Photoinduced charge and energy transfer involving fullerene derivatives
    Koeppe, R.
    Sariciftci, N. S.
    [J]. PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2006, 5 (12) : 1122 - 1131
  • [22] Koppe M, 2002, MOL CRYST LIQ CRYST, V385, P221, DOI [10.1080/713738796, 10.1080/10587250290113123]
  • [23] SOLID C-60 - A NEW FORM OF CARBON
    KRATSCHMER, W
    LAMB, LD
    FOSTIROPOULOS, K
    HUFFMAN, DR
    [J]. NATURE, 1990, 347 (6291) : 354 - 358
  • [24] C-60 - BUCKMINSTERFULLERENE, THE CELESTIAL SPHERE THAT FELL TO EARTH
    KROTO, HW
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (02) : 111 - 129
  • [25] C-60 - BUCKMINSTERFULLERENE
    KROTO, HW
    HEATH, JR
    OBRIEN, SC
    CURL, RF
    SMALLEY, RE
    [J]. NATURE, 1985, 318 (6042) : 162 - 163
  • [26] Demonstration of net gain at 1550 nm in an erbium-doped polymer single mode rib waveguide
    Le Quang, Anh Quoc
    Hierle, Rolland
    Zyss, Joseph
    Ledoux, Isabelle
    Cusmai, Giuseppe
    Costa, Raffaella
    Barberis, Angelo
    Pietralunga, Silvia Maria
    [J]. APPLIED PHYSICS LETTERS, 2006, 89 (14)
  • [27] Local carboxyfullerene protects cortical infarction in rat brain
    Lin, AMY
    Fang, SF
    Lin, SZ
    Chou, CK
    Luh, TY
    Ho, LT
    [J]. NEUROSCIENCE RESEARCH, 2002, 43 (04) : 317 - 321
  • [28] McGehee MD, 1999, ADV MATER, V11, P1349, DOI 10.1002/(SICI)1521-4095(199911)11:16<1349::AID-ADMA1349>3.0.CO
  • [29] 2-W
  • [30] SYNTHESIS + FLUORESCENCE OF SOME TRIVALENT LANTHANIDE COMPLEXES
    MELBY, LR
    ABRAMSON, E
    CARIS, JC
    ROSE, NJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (23) : 5117 - +
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