Luminescent Tags on Fullerenes: Eu3+ Complexes with Pendant Fullerenes

被引：8
作者：
Fuchsbatter, Anita [1 ]
Troshina, Olesya A. [2 ]
Troshin, Pavel A. [2 ]
Koeppe, Robert [1 ]
Lyubovskaya, Rimma N. [2 ]
Sariciftci, Niyazi Serdar [1 ]
机构：
[1] Johannes Kepler Univ Linz, Linz Inst Organ Solar Cells, A-4040 Linz, Austria
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
来源：
ADVANCED FUNCTIONAL MATERIALS | 2008年 / 18卷 / 18期
关键词：
D O I：
10.1002/adfm.200800377
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel fullerene-containing Eu (III) complexes are obtained by mixing a fullerene derivative bearing chelating pyridinyl groups with an Eu (III) complex possessing three coordinated 4,4,4,-trifluoro-1-(2-naphtyl)-1,3-butanedione residues and two water molecules. One of the complexes designed is formed in water using a water-soluble fullerene derivative as a precursor material. We investigate the photophysical properties of this new type of highly soluble self-assembled fullerene-derivative Eu3+ coordination compounds. A strong emission line of the Eu3+ 4f-4f transition is recorded under excitation with UV irradiation. The behaviour of the complexes in organic matrices and water is studied as the first steps towards luminescence tagged fullerene derivatives for use in biomedicine and optoelectronics.
引用
收藏
页码：2808 / 2814
页数：7
相关论文
共 51 条
  • [1] Aborgast J. W., 1991, J PHYS CHEM-US, V95, P11
  • [2] Sequence-specific modification of guanosine in DNA by a C-60-linked deoxyoligonucleotide: Evidence for a non-singlet oxygen mechanism
    An, YZ
    Chen, CHB
    Anderson, JL
    Sigman, DS
    Foote, CS
    Rubin, Y
    [J]. TETRAHEDRON, 1996, 52 (14) : 5179 - 5189
  • [3] PHOTOPHYSICAL PROPERTIES OF C-70
    ARBOGAST, JW
    FOOTE, CS
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) : 8886 - 8889
  • [4] Photodynamic therapy in dermatology - an update
    Babilas, P
    Karrer, S
    Sidoroff, A
    Landthaler, M
    Szeimies, RM
    [J]. PHOTODERMATOLOGY PHOTOIMMUNOLOGY & PHOTOMEDICINE, 2005, 21 (03) : 142 - 149
  • [5] Fullerene derivatives: an attractive tool for biological applications
    Bosi, S
    Da Ros, T
    Spalluto, G
    Prato, M
    [J]. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2003, 38 (11-12) : 913 - 923
  • [6] BOUTORINE AS, 1994, ANGEW CHEM INT EDIT, V33, P2462
  • [7] Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO
  • [8] 2-A
  • [9] A highly water-soluble dendro[60]fullerene
    Brettreich, M
    Hirsch, A
    [J]. TETRAHEDRON LETTERS, 1998, 39 (18) : 2731 - 2734
  • [10] Quenching of electronically excited Ln3+ ions by C60 fullerene
    Bulgakov, R. G.
    Gatimov, D. I.
    Ponomareva, Yu. G.
    Nevyadovskii, E. Yu.
    Gainetdinov, R. Kh.
    [J]. RUSSIAN CHEMICAL BULLETIN, 2006, 55 (06) : 955 - 960
123456