Relativistic Effects in Chemistry: More Common Than You Thought

被引：441
作者：
Pyykko, Pekka [1 ]
机构：
[1] Univ Helsinki, Dept Chem, FI-00014 Helsinki, Finland
来源：
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 63 | 2012年 / 63卷
关键词：
Dirac equation; heavy-element chemistry; gold; lead-acid battery; QUANTUM-CHEMICAL INVESTIGATIONS; DENSITY-FUNCTIONAL-THEORY; ANIONIC GOLD CLUSTERS; SPIN-ORBIT; TRANSITION-METAL; ELECTRONIC-STRUCTURE; CO OXIDATION; SYMMETRY; STABILITY; MOLECULE;
D O I：
10.1146/annurev-physchem-032511-143755
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Relativistic effects can strongly influence the chemical and physical properties of heavy elements and their compounds. This influence has been noted in inorganic chemistry textbooks for a couple of decades. This review provides both traditional and new examples of these effects, including the special properties of gold, lead-acid and mercury batteries, the shapes of gold and thallium clusters, heavy-atom shifts in NMR, topological insulators, and certain specific heats.
引用
收藏
页码：45 / 64
页数：20
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