The assembly line: Self-assembling nanocars

被引:19
作者
Sasaki, Takashi
Guerrero, Jason M.
Tour, James M. [1 ]
机构
[1] Rice Univ, Dept Chem, Houston, TX 77005 USA
关键词
D O I
10.1016/j.tet.2008.05.074
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Certain molecular structures that have controlled rolling properties on surfaces have been termed as nanocars. The syntheses of nanocars are generally multi-stepped. We report here the synthesis of two nanocars by a process resembling an assembly line where front and rear portions are attached using hydrogen bonding and metal complexation. Nanocars 1a and 2a,b were designed using 2-pyridone moieties for hydrogen bonding and terpyridyl ligands for metal complexation, respectively. (C) 2008 Elsevier Ltd. All rights reserved
引用
收藏
页码:8522 / 8529
页数:8
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