Chromogenic detection of Sarin by discolouring decomplexation of a metal coordination complex

被引：32
作者：
Ordronneau, Lucie [1 ]
Carella, Alexandre [1 ]
Pohanka, Miroslav [2 ]
Simonato, Jean-Pierre [1 ]
机构：
[1] CEA Liten, DTNM, LCRE, F-38054 Grenoble 9, France
[2] Univ Def, Fac Mil Hlth Sci, Hradec Kralove 50001, Czech Republic
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 79期
关键词：
CHEMICAL WARFARE AGENTS; FIELD-EFFECT TRANSISTORS; NERVE-AGENT; SENSORS; MIMICS; SPECTROMETRY; DESTRUCTION; SIMULANT; ASSAY;
D O I：
10.1039/c3cc45029e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An innovative chromogenic sensing concept based on decomplexation of a tris-(bipyridine)iron(II) coordination complex has been developed for the detection of organophosphorus nerve agents. It was evaluated both on a simulant and real Sarin in vapour and liquid phases.
引用
收藏
页码：8946 / 8948
页数：3
相关论文
共 31 条
[1]   Chemical approaches for detection and destruction of nerve agents [J].
Ajami, Dariush ;
Rebek, Julius, Jr. .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2013, 11 (24) :3936-3942
[2]  
[Anonymous], 1999, LANGES HDB CHEM, V15
[3]   Discrimination of nerve gases mimics and other organophosphorous derivatives in gas phase using a colorimetric probe array [J].
Chulvi, Katherine ;
Gavina, Pablo ;
Costero, Ana M. ;
Gil, Salvador ;
Parra, Margarita ;
Gotor, Raul ;
Royo, Santiago ;
Martinez-Manez, Ramon ;
Sancenon, Felix ;
Vivancos, Jose-L. .
CHEMICAL COMMUNICATIONS, 2012, 48 (81) :10105-10107
[4]   Development of an autonomous detector for sensing of nerve agents based on functionalized silicon nanowire field-effect transistors [J].
Clavaguera, Simon ;
Raoul, Nicolas ;
Carella, Alexandre ;
Delalande, Michael ;
Celle, Caroline ;
Simonato, Jean-Pierre .
TALANTA, 2011, 85 (05) :2542-2545
[5]   Sub-ppm Detection of Nerve Agents Using Chemically Functionalized Silicon Nanoribbon Field-Effect Transistors [J].
Clavaguera, Simon ;
Carella, Alexandre ;
Caillier, Laurent ;
Celle, Caroline ;
Pecaut, Jacques ;
Lenfant, Stephane ;
Vuillaume, Dominique ;
Simonato, Jean-Pierre .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (24) :4063-4066
[6]   Selective Detection of Nerve Agent Simulants by Using Triarylmethanol-Based Chromogenic Chemodosimeters [J].
Costero, Ana M. ;
Parra, Margarita ;
Gil, Salvador ;
Gotor, Raul ;
Martinez-Manez, Ramon ;
Sancenon, Felix ;
Royo, Santiago .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 2012 (26) :4937-4946
[7]   Chromo-Fluorogenic Detection of Nerve-Agent Mimics Using Triggered Cyclization Reactions in Push-Pull Dyes [J].
Costero, Ana M. ;
Parra, Margarita ;
Gil, Salvador ;
Gotor, Raul ;
Mancini, Pedro M. E. ;
Martinez-Manez, Ramon ;
Sancenon, Felix ;
Royo, Santiago .
CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (07) :1573-1585
[8]   Chromogenic detection of nerve agent mimics [J].
Costero, Ana M. ;
Gil, Salvador ;
Parra, Margarita ;
Mancini, Pedro M. E. ;
Martinez-Manez, Ramon ;
Sancenon, Felix ;
Royo, Santiago .
CHEMICAL COMMUNICATIONS, 2008, (45) :6002-6004
[9]   Fluorescent sensors for organophosphorus nerve agent mimics [J].
Dale, TJ ;
Rebek, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (14) :4500-4501
[10]   Hydroxy Oximes as Organophosphorus Nerve Agent Sensors [J].
Dale, Trevor J. ;
Rebek, Julius, Jr. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (42) :7850-7852
1234