Organic-Inorganic Interpenetrating Polymer Networks and Hybrid Polymer Materials Prepared by Frontal Polymerization

被引：19

作者：

Illescas, Javier ^{[1
,2
]}

Sanna, Roberta ^{[2
,3
]}

Alzari, Valeria ^{[2
]}

Nuvoli, Daniele ^{[2
]}

Casu, Mariano ^{[3
]}

Sanna, Roberta ^{[2
,3
]}

Rivera, Ernesto ^{[1
]}

Mariani, Alberto ^{[2
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Invest Mat, Mexico City 04510, DF, Mexico

[2] Univ Sassari, Dipartimento Chim & Farm, Local INSTM Unit, I-07100 Sassari, Italy

[3] Univ Cagliari, Dipartimento Sci Chim & Geol, Cittadella Univ Monserrato, I-09042 Monserrato, Italy

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2013年 / 51卷 / 21期

关键词：

acrylic polymers; frontal polymerization; hydrogels; interpenetrating networks (IPN); radical polymerization; SOLVENT-FREE SYNTHESIS; FUNCTIONALIZED SILICA; RESPONSIVE POLYMERS; EPOXY-RESINS; HYDROGELS; NANOCOMPOSITES; GRAPHENE; POLYURETHANE; MONOMERS; FILLERS;

D O I：

10.1002/pola.26882

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Novel polyacrylamide-based hydrogels containing 3-(trimethoxysilyl)propyl methacrylate and/or tetraethoxy silane were synthesized by means of frontal polymerization, using ammonium persulfate as initiator, N,N-methylene bisacrylamide as crosslinking agent and dimethyl sulfoxide as solvent. The obtained samples were treated at pH of 2 or 5 to induce the sol-gel reaction and evaluate their swelling behavior in the conditions. The occurrence of this reaction was assessed by solid-state NMR. Moreover, the thermal properties of the dry materials were studied by differential scanning calorimetry and thermal gravimetric analysis, and their water-contact angles were measured. It was found that the amount of Si affects the extent of swelling and the hydrophilicity of the resulting materials. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4618-4625

引用

页码：4618 / 4625

页数：8

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[1] In situ production of high filler content graphene-based polymer nanocomposites by reactive processing [J].