Structural and luminescence characterization of synthetic Cr-doped Ni3(PO4)2

被引：10

作者：

Correcher, V. ^{[1
]}

Isasi, J. ^{[2
]}

Cubero, A. ^{[2
]}

Perez, M. ^{[2
]}

Aldama, I. ^{[2
]}

Arevalo, P. ^{[2
]}

Castillo, J. F. ^{[3
]}

Garcia-Guinea, J. ^{[4
]}

机构：

[1] CIEMAT, E-28040 Madrid, Spain

[2] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan 1, E-28040 Madrid, Spain

[3] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Fis 1, E-28040 Madrid, Spain

[4] CSIC, Museo Nacl Ciencias Nat, E-28006 Madrid, Spain

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2013年 / 74卷 / 12期

关键词：

Sol-gel growth; X-ray diffraction; Luminescence; THERMOLUMINESCENCE; MICROSTRUCTURE; QUARTZ;

D O I：

10.1016/j.jpcs.2013.05.029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ni3-xCr2x/3(PO4)(2) (x=0 and 0.02) microcrystalline powders were obtained as single phases via a modified sol-gel Pechini-type in situ polymerizable complex method. The samples were characterized using scanning electron microscopy, X-ray diffraction, cathodoluminescence (CL), and thermoluminescence cm techniques. We found that Cr3+ doping modified the average particle and distribution. The mean particle size was 0.441 mu m for Ni-3(PO4)(2) and 0.267 mu m for Ni2.98C0.013(PO4)(2). The results also reveal that Cr3+ doping notably enhanced the CL and TL UV-blue emission. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：1678 / 1682

页数：5

共 11 条

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[2]

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[3]

Greenwood N. N., 2012, Chemistry of the Elements

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