Thermal Cracking of Hydrocarbon Aviation Fuels in Regenerative Cooling Microchannels

被引:264
作者
Jiang, Rongpei [1 ]
Liu, Guozhu [1 ]
Zhang, Xiangwen [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
C-10-C-14; NORMAL-ALKANES; HEAT-TRANSFER; PRODUCT DISTRIBUTIONS; N-DODECANE; KINETICS; DECOMPOSITION; PYROLYSIS; KEROSENE; PROPELLANTS; DEGRADATION;
D O I
10.1021/ef400367n
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Regenerative cooling with hydrocarbon aviation fuels on board is taken as a promising technology for the thermal management system of next-generation aircraft. An improved methodology of an electrically heated tube (1 mm i.d.), i.e., applying the variable reactor tube length to carry on thermal cracking of supercritical hydrocarbon aviation fuels as the electric current heating maintains constant, was proposed to experimentally obtain detailed information on the local concentration and temperature along the microchannels of a heat exchanger. For the first time a series of experimental data on detailed local chemical compositions of cracked hydrocarbon fuel along the cooling microchannels were reported under supercritical conditions (5 MPa, 680-700 degrees C), and the calculated thermodynamic properties, velocity, and residence times along the tube were also reported. A modified molecular reaction model consisting of 18 species and 24 reactions was developed to predict thermal cracking of hydrocarbon aviation fuels in a wide range of cracking conversion (up to 86%). The work is significant for the design of regenerative cooling structures in predicting the local chemical compositions, estimating thermophysical properties, and coking of the cracked hydrocarbon fuels for heat transfer analysis.
引用
收藏
页码:2563 / 2577
页数:15
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