Triarylphosphanes with Dendritically Arranged Tetraethylene Glycol Moieties at the Periphery: An Efficient Ligand for the Palladium-Catalyzed Suzuki-Miyaura Coupling Reaction

被引：84

作者：

Fujihara, Tetsuaki ^{[1
]}

Yoshida, Shohei ^{[1
]}

Ohta, Hidetoshi ^{[1
]}

Tsuji, Yasushi ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 43期

关键词：

dendrimers; palladium; phosphanes; Suzuki-Miyaura coupling;

D O I：

10.1002/anie.200802683

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Peripheral vision: A second generation dendritic phosphane, with tetraethylene glycol (TEG) moieties at the periphery, has been designed and prepared (see structure). It is particularly effective as a ligand for the title transformation when using aryl chloride substrates. To realize high catalytic activity, the TEG groups must be connected to the phosphane framework. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8310 / 8314

页数：5

共 72 条

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