Coordination chemistry of arylhydrazones of methylene active compounds

被引:99
作者
Mahmudov, Kamran T. [1 ,2 ]
Kopylovich, Maximilian N. [1 ]
Pombeiro, Armando J. L. [1 ]
机构
[1] Univ Tecn Lisboa, Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal
[2] Baku State Univ, Dept Chem, AZ-1148 Baku, Azerbaijan
关键词
Arylhydrazones of methylene active compounds; Metal complexes; Tautomeric equilibria; Template synthesis; Catalysis; JAPP-KLINGEMANN REACTION; OPTICAL-RECORDING MEDIA; HYDROGEN-BOND THEORY; BETA-DIKETONES; COPPER(II) COMPLEXES; CRYSTAL-STRUCTURE; STABILITY-CONSTANTS; METAL-COMPLEXES; AZO DERIVATIVES; X-RAY;
D O I
10.1016/j.ccr.2012.12.016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The methods of synthesis of arylhydrazones of methylene active compounds (AHMACs) as well as the preparation and properties of their metal complexes are reviewed. Nuclearity, supramolecular arrangements and other features (e.g., solubility, redox potentials, catalytic and antibacterial activities) of the complexes can be controlled by the introduction of different substituents to the methylene active and/or the aromatic fragments of AHMAC and by variation of metal-ions used in the synthesis. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1244 / 1281
页数:38
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