Open-Shell First-Row Transition-Metal Polyhydride Complexes Based on the fac-[RuH3(PR3)3]- Building Block

被引：18

作者：

Plois, Markus ^{[1
,2
]}

Hujo, Waldemar ^{[3
]}

Grimme, Stefan ^{[4
]}

Schwickert, Christian ^{[1
]}

Bill, Eckhard ^{[5
]}

de Bruin, Bas ^{[6
]}

Poettgen, Rainer ^{[1
]}

Wolf, Robert ^{[1
,2
]}

机构：

[1] Inst Anorgan & Analyt Chem, D-48149 Munster, Germany

[2] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

[3] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

[4] Univ Bonn, Mulliken Ctr Theoret Chem, Inst Phys & Theoret Chem, D-53115 Bonn, Germany

[5] Max Planck Inst Chem Energy Convers, D-45470 Mulheim An Der Ruhr, Germany

[6] Univ Amsterdam, Vant Hoff Inst Mol Sci HIMS, NL-1098 XH Amsterdam, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 04期

关键词：

EPR spectroscopy; hydrides; iron; open-shell complexes; ruthenium; X-RAY; ACTIVE-SITE; NEUTRON-DIFFRACTION; MOLECULAR-STRUCTURE; CHROMIUM HYDRIDE; HYDROGENATION; REACTIVITY; MECHANISM; CATION; DECOMPOSITION;

D O I：

10.1002/anie.201205209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-spin hydrides: A new class of stable paramagnetic polyhydride complexes [M{Ru(μ-H)3(PTol3)3}2] (M=Cr-Ni) with an unprecedented trinuclear arrangement has been synthesized. The high-spin central 3d metal ion is sandwiched between six hydride ligands in a distorted octahedral fashion. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1314 / 1318

页数：5

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