A [Mn18Dy] SMM resulting from the targeted replacement of the central MnII in the S=83/2 [Mn19]-aggregate with DyIII

被引：191

作者：

Ako, Ayuk M. ^{[1
]}

Mereacre, Valeriu ^{[1
]}

Clerac, Rodolphe ^{[2
,3
]}

Wernsdorfer, Wolfgang ^{[4
]}

Hewitt, Ian J. ^{[1
]}

Anson, Christopher E. ^{[1
]}

Powell, Annie K. ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

[2] Equipe Mat Mol Magnet, Ctr Rech Paul Pascal, UPR 8641, CNRS, F-33600 Pessac, France

[3] Univ Bordeaux, UPR 8641, F-33600 Pessac, France

[4] CNRS, Inst Neel, F-38042 Grenoble 9, France

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 05期

关键词：

SINGLE-MOLECULE MAGNETS; HIGH-SPIN MOLECULES; GROUND-STATE; SOLID-STATE; COMPLEXES; MAGNETIZATION; ANISOTROPY; MANGANESE; MN-10;

D O I：

10.1039/b814614d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anisotropy can be introduced into the [Mn-19]-aggregate, which currently has the highest known spin ground state of S = 83/2, by the targeted replacement of the central Mn-II cation with Dy-III leading to a [Mn18Dy] complex with the same core topology showing slow relaxation of the magnetisation.

引用

页码：544 / 546

页数：3

共 31 条

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