Fast selective oxidation of alcohols under solvent-free conditions

被引：8

作者：

Saffar-Teluri, Ali ^{[1
]}

机构：

[1] Islamic Azad Univ, Fac Mat Sci & Engn, Najafabad Branch, Najafabad, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2013年 / 39卷 / 07期

关键词：

Selective oxidation; Alcohols; Acetic anhydride; Solvent-free; EFFICIENT REAGENT; CARBONYL-COMPOUNDS; SECONDARY ALCOHOLS; PYRIDINIUM DICHROMATE; ACETIC-ANHYDRIDE; BENZYL ALCOHOL; CHLOROCHROMATE; SILICA; COMPLEX; MILD;

D O I：

10.1007/s11164-012-0846-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination of acetic anhydride, H2SO4-nano silica, wet-SiO2 (60 %), and K2Cr2O7 as a new oxidizing system for the selective oxidation of different types of alcohols to the corresponding aldehydes and ketones at room temperature under solvent-free conditions is introduced. Mild reaction conditions, high yields of the products, short reaction time, no further oxidation to the corresponding carboxylic acid, and easy work-up make this new system a useful method for oxidizing alcohols.

引用

页码：3337 / 3343

页数：7

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