Self-Assembled Water Molecules as a Functional Valve for a High-Pressure Nanocontainer

被引：4

作者：

Chen, H. Y. ^{[1
,4
,5
]}

Sun, D. Y. ^{[1
]}

Gong, X. G. ^{[2
,3
]}

Liu, Zhi-Feng ^{[4
,5
]}

机构：

[1] E China Normal Univ, Dept Phys, Shanghai 200062, Peoples R China

[2] Fudan Univ, Surface Phys Lab, Shanghai 200433, Peoples R China

[3] Fudan Univ, Dept Phys, Shanghai 200433, Peoples R China

[4] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[5] Chinese Univ Hong Kong, Ctr Sci Modeling & Computat, Shatin, Hong Kong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 07期

关键词：

carbon nanotubes; high-pressure chemistry; hydrogen storage; molecular dynamics; WALLED CARBON NANOTUBES; HYDROGEN-STORAGE; PHASE;

D O I：

10.1002/anie.201207463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon nanotubes: The end section of a carbon nanotube, cut by acid treatment, contains hydrophilic oxygen groups, around which water molecules can assemble to block the entry of the tube. Hydrogen of pressures up to 10 000 bar can be locked inside the tube by such an "aqueous valve" (see picture). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1973 / 1976

页数：4

共 27 条

[1] Molecular Simulation of Water in Carbon Nanotubes [J].

Alexiadis, Alessio ;

Kassinos, Stavros .

CHEMICAL REVIEWS, 2008, 108 (12) :5014-5034

[2] In situ observations of self-repairing single-walled carbon nanotubes [J].

Boerrnert, Felix ;

Gorantla, Sandeep ;

Bachmatiuk, Alicja ;

Warner, Jamie H. ;

Ibrahim, Imad ;

Thomas, Juergen ;

Gemming, Thomas ;

Eckert, Juergen ;

Cuniberti, Gianaurelio ;

Buechner, Bernd ;

Ruemmeli, Mark H. .

PHYSICAL REVIEW B, 2010, 81 (20)

[3] Uniform, Dense Arrays of Vertically Aligned, Large-Diameter Single-Walled Carbon Nanotubes [J].

Han, Zhao Jun ;

Ostrikov, Kostya .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (13) :6018-6024

[4] PHASE-TRANSITION IN SOLID MOLECULAR-HYDROGEN AT ULTRAHIGH PRESSURES [J].

HEMLEY, RJ ;

MAO, HK .

PHYSICAL REVIEW LETTERS, 1988, 61 (07) :857-860

[5] THERMODYNAMIC PROPERTIES OF HYDROGEN AT PRESSURES UP TO 1 MBAR AND TEMPERATURES BETWEEN 100-K AND 1000-K [J].

HEMMES, H ;

DRIESSEN, A ;

GRIESSEN, R .

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1986, 19 (19) :3571-3585

[6] Hydrogen as a fuel for today and tomorrow: expectations for advanced hydrogen storage materials/systems research [J].

Hirose, Katsuhiko .

FARADAY DISCUSSIONS, 2011, 151 :11-18

[7] Controlling the growth of single-walled carbon nanotubes on surfaces using metal and non-metal catalysts [J].

Hong, Guo ;

Chen, Yabin ;

Li, Pan ;

Zhang, Jin .

CARBON, 2012, 50 (06) :2067-2082

[8] Molecules in carbon nanotubes [J].

Khlobystov, AN ;

Britz, DA ;

Briggs, GAD .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (12) :901-909

[9] Carbon Nanotubes: From Nano Test Tube to Nano-Reactor [J].

Khlobystov, Andrei N. .

ACS NANO, 2011, 5 (12) :9306-9312

[10] Enhancement of adsorption inside of single-walled nanotubes: opening the entry ports [J].

Kuznetsova, A ;

Mawhinney, DB ;

Naumenko, V ;

Yates, JT ;

Liu, J ;

Smalley, RE .

CHEMICAL PHYSICS LETTERS, 2000, 321 (3-4) :292-296

← 1 2 3 →