Enhanced Electrogenerated Chemiluminescence in Thermoresponsive Microgels

被引：73

作者：

Pinaud, Florent ^{[1
]}

Russo, Lorenzo ^{[1
]}

Pinet, Sandra ^{[1
]}

Gosse, Isabelle ^{[1
]}

Ravaine, Valerie ^{[1
]}

Sojic, Neso ^{[1
]}

机构：

[1] Univ Bordeaux, ENSCBP, CNRS UMR 5255, Inst Mol Sci, F-33607 Pessac, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 15期

关键词：

TEMPERATURE-DEPENDENCE; SYSTEM; OXIDATION; HYDROGELS; EMISSION; ELECTROCHEMILUMINESCENCE; ACETONITRILE; EFFICIENCY; COMPLEXES; COLLOIDS;

D O I：

10.1021/ja401011j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemistry, photoluminescence and electrogenerated chemiluminescence of thermoresponsive redox microgels were investigated. For the first time, reversible ECL enhancement is demonstrated in stimuli-responsive 100-nm microgel particles. Such an unexpected amplification reached 2 orders of magnitude, and it is intrinsically correlated with the collapse of the microgel particles. The swell-collapse transition decreases the average distance between adjacent redox sites and favors the electron-transfer processes in the microgels resulting in the enhanced ECL emission.

引用

页码：5517 / 5520

页数：4

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