Recent Advances in the Asymmetric Conjugate Addition Reactions of Phosphorus Nucleophiles to Electron-Deficient Alkenes

被引：32
作者：
Li, Zhen [1 ]
Duan, Weiliang [2 ]
机构：
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 36卷 / 08期
基金：
中国国家自然科学基金;
关键词：
asymmetric addition; phosphorus nucleophiles; chiral phosphorus compounds; electron-deficient alkenes; ALPHA; BETA-UNSATURATED N-ACYLPYRROLES; PALLADIUM-CATALYZED 1,4-ADDITION; PCN PINCER PALLADIUM(II); DIALKYL PHOSPHINE OXIDES; ENANTIOSELECTIVE HYDROPHOSPHINATION; MICHAEL ADDITION; ACTIVATED OLEFINS; SULFONIC ESTERS; P-C; DIARYLPHOSPHINES;
D O I：
10.6023/cjoc201602018
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral phosphines are very useful in the fields of asymmetric catalysis, pharmaceutical chemistry, and materials. These compounds have been used as ligands coordinated to transition metals or organocatalysts in various reactions to furnish optically active products with high efficiency. Asymmetric phosphorus-addition reaction can be utilized for the direct preparation of chiral phosphorus compounds. This review summarizes the recent progress in the field of enantioselective phosphorus-addition reactions. Several examples of transition metal- and organocatalyst-promoted asymmetric hydrophosphination reactions of electron-deficient alkenes have been introduced.
引用
收藏
页码：1805 / 1813
页数：9
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