Adsorption Kinetics and Equilibrium of Cu(II) from Aqueous Solution by Polyaniline/Coconut Shell-Activated Carbon Composites

被引：11
|
作者：
Fang, Xiaohong [1 ]
Xu, Xiaochen [1 ]
Wang, Shanshan [1 ]
Wang, Dong [1 ]
机构：
[1] Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn, Dalian 116024, Peoples R China
来源：
JOURNAL OF ENVIRONMENTAL ENGINEERING | 2013年 / 139卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Polyaniline; Coconut shell-activated carbon; Cu(II); Adsorption kinetics; Adsorption equilibrium; COPPER; REMOVAL; IONS; CAPACITY; MONTMORILLONITE; BIOSORPTION; ADSORBENTS; CHITOSAN; SAWDUST; BIOMASS;
D O I：
10.1061/(ASCE)EE.1943-7870.0000743
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Polyaniline/coconut shell-activated carbon (PANI/GAC) composites were fabricated by chemical oxidative polymerization of aniline monomers with GAC as the supporting materials. These prepared PANI/GAC composites were characterized by scanning electron microscopy, N2 adsorption-desorption analysis, and Fourier transform infrared spectroscopy. The effects of various parameters, including aqueous pH, contact time, the initial concentration of Cu(II), and temperature (288-323K) on the Cu(II)'s adsorption, were investigated in detail. Results showed that the adsorption maximum occurs at around pH 5.5 and adsorption equilibrium was achieved in 90min at 400mgL-1 Cu(II) concentration. The adsorption process followed the pseudo second-order kinetics, and the adsorption equilibrium data fit well with the Langmuir isotherm. Thermodynamic parameters indicated that the adsorption processes were endothermic, spontaneous, and more favorable at a higher temperature.
引用
收藏
页码：1279 / 1284
页数：6
相关论文
共 50 条
  • [1] Adsorption kinetics and equilibrium of copper from aqueous solutions using hazelnut shell activated carbon
    Demirbas, E.
    Dizge, N.
    Sulak, M. T.
    Kobya, M.
    CHEMICAL ENGINEERING JOURNAL, 2009, 148 (2-3) : 480 - 487
  • [2] Adsorption of ammonium ion by coconut shell-activated carbon from aqueous solution: kinetic, isotherm, and thermodynamic studies
    Boopathy, Ramasamy
    Karthikeyan, Sekar
    Mandal, Asit Baran
    Sekaran, Ganesan
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2013, 20 (01) : 533 - 542
  • [3] Optimum isotherm by linear and nonlinear regression methods for lead (II) ions adsorption from aqueous solutions using synthesized coconut shell-activated carbon (SCSAC)
    Okpara, Onyedikachi Godwin
    Ogbeide, Osareme Mercy
    Ike, Ozoemena Christain
    Menechukwu, Kosoluchi Chisom
    Ejike, Eric Chidozie
    TOXIN REVIEWS, 2021, 40 (04) : 901 - 914
  • [4] Kinetic and isotherm studies for adsorption of Pb(II) from aqueous solution onto coconut shell activated carbon
    El-Deen, G. E. Sharaf
    El-Deen, S. E. A. Sharaf
    DESALINATION AND WATER TREATMENT, 2016, 57 (59) : 28910 - 28931
  • [5] Adsorption of Cu(II) from Aqueous Solution by Peanut Shell
    Gong Zhengjun
    Tang Congcong
    Sun Caiyun
    Tang Lu
    Chen Jun
    RENEWABLE AND SUSTAINABLE ENERGY, PTS 1-7, 2012, 347-353 : 1852 - 1855
  • [6] Coconut Shell Biochar for Removal of Cu(II) from Aqueous Solution
    Hasana, Nur Hanani
    Wahi, Rafeah
    Yusof, Yusralina
    Yusof, Wan Roslina Wan
    Manan, Zeti Akhtar Abdul
    PAKISTAN JOURNAL OF ANALYTICAL & ENVIRONMENTAL CHEMISTRY, 2020, 21 (02) : 280 - 292
  • [7] Kinetics and equilibrium study for the adsorption of lysine on activated carbon derived from coconut shell
    Yang, Jinbei
    Han, Shuicui
    DESALINATION AND WATER TREATMENT, 2018, 120 : 261 - 271
  • [8] Kinetic and equilibrium studies of the adsorption of Cd(II) from aqueous solutions by wood apple shell activated carbon
    Sartape, Ashish S.
    Mandhare, Aniruddha M.
    Salvi, Prathmesh P.
    Pawar, Dattatraya K.
    Kolekar, Sanjay S.
    DESALINATION AND WATER TREATMENT, 2013, 51 (22-24) : 4638 - 4650
  • [9] Adsorption kinetics of Cd(II), Zn(II) and Cu(II) and their mixtures from an aqueous solution onto immobilized activated sludge
    Filipkowska, Urszula
    Kuczajowska-Zadrozna, Malgorzata
    DESALINATION AND WATER TREATMENT, 2020, 180 : 284 - 292
  • [10] Adsorption Equilibrium and Kinetics of Pb(II) from Aqueous Solution by Modified Walnut Shell
    Cheng, Liping
    Sun, Li
    Xue, Weilan
    Zeng, Zuoxiang
    Li, Shenmaishang
    ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, 2016, 35 (06) : 1724 - 1731
12345