Single-crystal-to-single-crystal guest exchange in columnar assembled brominated triphenylamine bis-urea macrocycles

被引:26
|
作者
Sindt, Ammon J. [1 ]
Smith, Mark D. [1 ]
Berens, Samuel [2 ]
Vasenkov, Sergey [2 ]
Bowers, Clifford R. [3 ]
Shimizu, Linda S. [1 ]
机构
[1] Univ South Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
[2] Univ Florida, Dept Chem Engn, Gainesville, FL 32611 USA
[3] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
基金
美国国家科学基金会;
关键词
METAL-ORGANIC-FRAMEWORKS; PHASE-TRANSITION; HIGH-PRESSURE; NANOTUBES; STORAGE;
D O I
10.1039/c9cc01725a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self-assembly of brominated triphenylamine bis-urea macrocycles affords robust porous materials. Urea hydrogen bonds organize these building blocks into 1-dimensional columns, which pack via halogen-aryl interactions. The crystals are stablewhen emptied, present two distinct absorption sites for Xe with restricted Xe diffusion, and exhibit single-crystal-to-single-crystal guest exchange.
引用
收藏
页码:5619 / 5622
页数:4
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