Single-crystal-to-single-crystal guest exchange in columnar assembled brominated triphenylamine bis-urea macrocycles

被引：26

作者：

Sindt, Ammon J. ^{[1
]}

Smith, Mark D. ^{[1
]}

Berens, Samuel ^{[2
]}

Vasenkov, Sergey ^{[2
]}

Bowers, Clifford R. ^{[3
]}

Shimizu, Linda S. ^{[1
]}

机构：

[1] Univ South Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

[2] Univ Florida, Dept Chem Engn, Gainesville, FL 32611 USA

[3] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 39期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC-FRAMEWORKS; PHASE-TRANSITION; HIGH-PRESSURE; NANOTUBES; STORAGE;

D O I：

10.1039/c9cc01725a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly of brominated triphenylamine bis-urea macrocycles affords robust porous materials. Urea hydrogen bonds organize these building blocks into 1-dimensional columns, which pack via halogen-aryl interactions. The crystals are stablewhen emptied, present two distinct absorption sites for Xe with restricted Xe diffusion, and exhibit single-crystal-to-single-crystal guest exchange.

引用

页码：5619 / 5622

页数：4

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