A new palladium(II) complex of a functionalized N-heterocyclic carbene: Synthesis, characterization and application in Suzuki-Miyaura cross-coupling reactions

被引：36

作者：

Linninger, Claudia S. ^{[1
]}

Herdtweck, Eberhardt ^{[1
]}

Hoffmann, Stephan D. ^{[2
]}

Herrmann, Wolfgang A. ^{[1
]}

Kuehn, Fritz E. ^{[1
]}

机构：

[1] Tech Univ Munich, Fak Chem, Lehrstuhl Anorgan Chem, D-85747 Garching, Germany

[2] Tech Univ Munich, Fak Chem, Lehrstuhl Anorgan Chem Schwerpunkt Neue Mat, D-85747 Garching, Germany

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2008年 / 890卷 / 1-3期

关键词：

Imidazolium salt; N-heterocyclic carbene; Palladium; Suzuki-Miyaura cross-coupling;

D O I：

10.1016/j.molstruc.2008.05.037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

trans-[PdBr2(NHC)Im] was prepared by reacting the corresponding imidazolium (Im) salt with palladium(H) acetate in dimethylsulfoxide in an in-situ reaction without generating a free carbene. Both the salt and the complex were characterized spectroscopically and by X-ray structure analysis. The complex was tested in homogeneous Suzuki-Miyaura cross-coupling reactions. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：192 / 197

页数：6

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