Synthesis, X-ray and solid state NMR studies on silver(I) silanethiolates.: Crystal structure of bis[(triphenylphosphine)-(tri-o-tolylsilanethiolato)silver(I)]-toluene(1/2), [{Ag[SSi(C6H4-Me-o)3](PPh3)}2]•2C6H5Me

被引：25
|
作者：
Chojnacki, J
Becker, B
Konitz, A
Potrzebowski, MJ
Wojnowski, W
机构：
[1] Gdansk Tech Univ, Dept Chem, PL-80952 Gdansk, Poland
[2] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 17期
关键词：
D O I：
10.1039/a903694f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of silver(I) trialkoxysilanethiolates [Ag(SSiR3)(PPh3)(2)], R = (BuO)-O-t, (BuO)-O-s or (PrO)-O-i, and triarylsilanethiolates [Ag(SSiR'(3))(PPh3)], R' = o-MeC6H4 or Ph, were obtained by reaction of [Ag(acac)(PPh3)(2)] with the respective silanethiols. Products were studied by H-1 NMR, CP MAS P-31 and Si-29 NMR in solution and/or in the solid state. A single-crystal X-ray structural analysis was carried on for [{Ag[SSi(C6H4Me-o)(3)](PPh3)}(2)]. 2C(6)H(5)Me.
引用
收藏
页码：3063 / 3068
页数：6
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