Synthesis, X-ray and solid state NMR studies on silver(I) silanethiolates.: Crystal structure of bis[(triphenylphosphine)-(tri-o-tolylsilanethiolato)silver(I)]-toluene(1/2), [{Ag[SSi(C6H4-Me-o)3](PPh3)}2]•2C6H5Me

被引：25

作者：

Chojnacki, J

Becker, B

Konitz, A

Potrzebowski, MJ

Wojnowski, W

机构：

[1] Gdansk Tech Univ, Dept Chem, PL-80952 Gdansk, Poland

[2] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a903694f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of silver(I) trialkoxysilanethiolates [Ag(SSiR3)(PPh3)(2)], R = (BuO)-O-t, (BuO)-O-s or (PrO)-O-i, and triarylsilanethiolates [Ag(SSiR'(3))(PPh3)], R' = o-MeC6H4 or Ph, were obtained by reaction of [Ag(acac)(PPh3)(2)] with the respective silanethiols. Products were studied by H-1 NMR, CP MAS P-31 and Si-29 NMR in solution and/or in the solid state. A single-crystal X-ray structural analysis was carried on for [{Ag[SSi(C6H4Me-o)(3)](PPh3)}(2)]. 2C(6)H(5)Me.

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收藏

页码：3063 / 3068

页数：6

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