Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of α,ω-difunctional chemical intermediates from renewable raw materials

被引：67

作者：

Jacobs, Tina ^{[1
]}

Rybak, Anastasiya ^{[1
]}

Meier, Michael A. R. ^{[1
]}

机构：

[1] Univ Appl Sci Oldenburg Ostfriesland Wilhelmshave, D-26723 Emden, Germany

来源：

APPLIED CATALYSIS A-GENERAL | 2009年 / 353卷 / 01期

关键词：

Olefin metathesis; Cross-metathesis; Renewable resources; Monomer; Fatty acid; Nylon; POLYMERIZATION; OLEFINS; CATALYST; ACRYLATE; INDUSTRY; OILS;

D O I：

10.1016/j.apcata.2008.10.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of alpha,omega-difunctional chemical intermediates from renewable resources via the cross-metathesis reactions with allyl chloride is described. Different ruthenium metathesis catalysts were investigated and the reaction conditions were optimized for high conversions in combination with high cross-metathesis selectivity. New building blocks and chemical intermediates from fatty acid derivates were thus obtained in catalytic reactions with low catalyst loadings under bulk conditions. Therefore, a new potential use of renewable raw materials for the synthesis of intermediates for Nylon-11 and Nylon-12 was demonstrated. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：32 / 35

页数：4

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