A new luminescent 3D metal-organic framework possessing a rare (3,5)-connected net which can be transformed from a 2D double layer

被引：40

作者：

He, Haiyan ^{[1
]}

Dai, Fangna ^{[1
]}

Sun, Daofeng ^{[1
]}

机构：

[1] Shandong Univ, Minist Educ, Sch Chem & Chem Engn, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China

来源：

DALTON TRANSACTIONS | 2009年 / 05期

关键词：

SINGLE-CRYSTAL TRANSFORMATION; LIGAND CHARGE-TRANSFER; COORDINATION POLYMER; 3-DIMENSIONAL NETWORK; HYDROTHERMAL SYNTHESIS; SORPTION PROPERTIES; BUILDING-BLOCKS; COMPLEXES; DESIGN; SQUARE;

D O I：

10.1039/b815935a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Applying a nonplanar dicarboxylate ligand, a new 3D metal-organic framework, Zn(TBDC1)(1/2)(TBDC2)(1/2) (1), possessing a rare (3,5)-connected net has been synthesized and characterized; complex 1 can be formed from a 2D double layer by thermally liberating the coordinated water and dmf molecules, simultaneous with luminescence-increased changes.

引用

页码：763 / 766

页数：4

共 61 条

[1] Intense fluorescence of metal-to-ligand charge transfer in [Pt(0)(binap)2] [binap=2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] [J].