Unification of the quantum and classical theories of methyl NMR

被引：1
作者：
Clough, S [1 ]
机构：
[1] Univ Nottingham, Sch Phys & Astron, Dept Phys, Nottingham NG7 2RD, England
来源：
SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1999年 / 14卷 / 02期
关键词：
quantum theory; classical theory; methyl NMR;
D O I：
10.1016/S0926-2040(99)00016-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The existing low and high temperature theories of methyl NMR are not linked because two conditions imposed on state functions in the low temperature theory are not compatible with the classical rotations on which the high temperature theory is based. The conditions do not occur in a geometrical theory of quantum phenomena in which particles and waves have separate roles. When applied to methyl dynamics, this theory covers the whole temperature range. (C) 1999 Elsevier Science B.V. All rights reserved.
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页码：73 / 79
页数：7
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