Preparation of Cu(OAc)2/MCM-41 catalyst and its application in the one-pot synthesis of 1,2,3-triazoles in water

被引：15

作者：

Hosseinzadeh, Rahman ^{[1
]}

Sepehrian, Hamid ^{[2
]}

Shahrokhi, Farshid ^{[1
]}

机构：

[1] Univ Mazandaran, Fac Chem, Dept Organ Chem, Babol Sar, Iran

[2] Nucl Sci & Technol Res Inst, Jaber Ibn Hayan Res Labs, Tehran, Iran

来源：

HETEROATOM CHEMISTRY | 2012年 / 23卷 / 05期

关键词：

ORGANIC-REACTIONS; COPPER NANOPARTICLES; TERMINAL ALKYNES; MOLECULAR-SIEVES; CLICK CHEMISTRY; AQUEOUS-MEDIA; CYCLOADDITION; HALIDES; AZIDE; FOCUS;

D O I：

10.1002/hc.21031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient one-pot synthesis of 1,2,3-triazoles via the three-component coupling reaction between benzyl or alkyl bromides, terminal alkynes, and sodium azide in the presence of catalytic amounts of Cu(OAc)2/MCM-41 catalyst has been described. This catalyst showed high catalytic activity and 1,4-regioselectivity for the [3 + 2]Huisgen cycloaddition. This method avoids isolation and handling of organic azides, using water as a solvent, and catalyst recycling makes this synthesis a truly green procedure. (C) 2012 Wiley Periodicals, Inc. Heteroatom Chem 23:415421, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.21031

引用

页码：415 / 421

页数：7

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