Preparation of a novel morphology nano-fibrous catalyst for olefin hydrogenation

被引:0
|
作者
Yu, JX [1 ]
Liu, TQ [1 ]
Zhao, SC [1 ]
机构
[1] Beijing Inst Petrochem Technol, Res Ctr Ecomat, Beijing 102617, Peoples R China
来源
Proceedings of the World Engineers' Convention 2004: Vol D, Environment Protection and Disaster Mitigation | 2004年
关键词
hydrogenation; polymer supported catalysts; palladium;
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A novel nano-fibrous catalyst was prepared in which palladium is coordinated with Poly (styrene-co-acrylonitrile), then the poly (styrene-coacrylonitrile) coordinated PdCl2 catalyst (PS-AN-Pd) were electrospun into nano fiber with electrospining technique. The complexes are highly active for the hydrogenation of a-olefin at room temperature under 1 atm. hydrogen pressure. In addition, it is found that the activity of these PS-AN-Pd catalyst is mainly affected by their N/Pd atomic ratio and its morphology.
引用
收藏
页码:301 / 303
页数:3
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