Nanowire interwoven NiCo2S4 nanowall arrays as promising anodes for lithium ion batteries

被引:62
作者
Zhu, F. [1 ,2 ]
Xia, H. [1 ,2 ]
Feng, T. [1 ,2 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Mat Sci & Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Nanjing Univ Sci & Technol, Herbert Gleiter Inst Nanosci, Nanjing 210094, Jiangsu, Peoples R China
基金
中国博士后科学基金;
关键词
Metal sulfides; Nanowires; Nanowalls; Lithium ion batteries; Anode; ELECTROCHEMICAL PROPERTIES; COMPOSITE; ELECTRODE; GRAPHENE;
D O I
10.1179/17535557A15Y.000000007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Metal sulfides have recently emerged as a new class of anode materials for lithium ion batteries. In this work, a facile method based on anion exchange reaction is reported to prepare nanowire interwoven NiCo2S4 nanowall arrays through topotactical transformation from the Ni-Co carbonate hydroxide precursor. The nanowire interwoven NiCo2S4 nanowall arrays are investigated as binder free anodes for lithium ion batteries. The electrochemical measurements reveal that the NiCo2S4 nanowall arrays possess large reversible capacity, good cycling stability and good rate capacity, making them promising anodes for advanced lithium ion batteries.
引用
收藏
页码:A53 / A57
页数:5
相关论文
共 28 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   Highly conductive NiCo2S4 urchin-like nanostructures for high-rate pseudocapacitors [J].
Chen, Haichao ;
Jiang, Jianjun ;
Zhang, Li ;
Wan, Houzhao ;
Qi, Tong ;
Xia, Dandan .
NANOSCALE, 2013, 5 (19) :8879-8883
[3]   Electrochemical properties of MnO2 nanorods as anode materials for lithium ion batteries [J].
Chen, Jingbo ;
Wang, Yaowu ;
He, Xiangming ;
Xu, Shengming ;
Fang, Mou ;
Zhao, Xiao ;
Shang, Yuming .
ELECTROCHIMICA ACTA, 2014, 142 :152-156
[4]   Synthesis of carbon coated Fe3O4/SnO2 composite beads and their application as anodes for lithium ion batteries [J].
Chen, Y. ;
Song, B. H. ;
Lu, L. ;
Xue, J. M. .
MATERIALS TECHNOLOGY, 2013, 28 (05) :254-259
[5]   Reactivity of transition metal (Co, Ni, Cu) sulphides versus lithium: The intriguing case of the copper sulphide [J].
Debart, A. ;
Dupont, L. ;
Patrice, R. ;
Tarascon, J. -M. .
SOLID STATE SCIENCES, 2006, 8 (06) :640-651
[6]   Challenges for Rechargeable Li Batteries [J].
Goodenough, John B. ;
Kim, Youngsik .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603
[7]   Graphene-Wrapped CoS Nanoparticles for High-Capacity Lithium-Ion Storage [J].
Gu, Yan ;
Xu, Yi ;
Wang, Yong .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (03) :801-806
[8]   Lithium insertion into transition-metal monosulfides: Tuning the position of the metal 4s band [J].
Kim, Youngsik ;
Goodenough, John B. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (38) :15060-15064
[9]   On the origin of the extra electrochemical capacity displayed by MO/Li cells at low potential [J].
Laruelle, S ;
Grugeon, S ;
Poizot, P ;
Dollé, M ;
Dupont, L ;
Tarascon, JM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (05) :A627-A634
[10]   A Fe2O3 nanoparticle/carbon aerogel composite for use as an anode material for lithium ion batteries [J].
Liu, Nianping ;
Shen, Jun ;
Liu, Dong .
ELECTROCHIMICA ACTA, 2013, 97 :271-277