Photosubstitution of the halide ligands (X-) in (η5-C5H5)Fe(CO)(PPh3)X

被引：4

作者：

Rudolf, B ^{[1
]}

Walendowska, J ^{[1
]}

Zakrzewski, J ^{[1
]}

机构：

[1] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 648卷 / 1-2期

关键词：

halide ligands; imidato ligands; photosubstitution;

D O I：

10.1016/S0022-328X(01)01447-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Irradiation of CpFe(CO)(PPh3)X, (CP = eta(5)-cyclopentadienyl, X = Cl, Br or 1), la-c, with white or red (lambda > 600 nm) light with maleimide or succinimide and di-iso-propyl amine (dipa) or ethyldi-iso-propyl amine (edipa) in dichloromethane leads to the efficient formation of CpFe(CO)(PPh3)(eta(1)-N-imidato) complexes 2a-b. Irradiation with white light of CpFe(CO)(PPh3)Br in dichloromethane in the presence of an excess of Br- (as tetrabutylammonium bromide) yields CpFe(CO)(PPh3)Br. These results are discussed in terms of possible photoinduced heterolysis of the iron-halide bond in la-c. (C) 2002 Elsevier Science B.V, All rights reserved.

引用

页码：293 / 296

页数：4

共 50 条

[21] PREPARATION AND SOME REACTIONS OF RESOLVED CHIRAL IRON COMPLEXES OF TYPE (ETA-5-C5H5)FE(CO) (PPH3)X
FLOOD, TC
MILES, DL
DISANTI, FJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, 172 (SEP3): : 165 - 165
[22] Synthesis, characterization and crystal structure of the bimetallic cyano-bridged [(η5-C5H5)(PPh3)2Ru(μ-CN)Ru(PPh3)2(η5-C5H5)][PF6]
Ornelas, C
Gandum, C
Mesquita, J
Rodrigues, J
Garcia, MH
Lopes, N
Robalo, MP
Nättinen, K
Rissanen, K
INORGANICA CHIMICA ACTA, 2005, 358 (08) : 2482 - 2488
[23] Diastereoselective conjugate additions to alkoxycarbene cations of the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)=C(OMe)CH=CHR]
Davies, Stephen G.
Easton, Robert J. C.
McKenna, Jeffrey M.
Polywka, Mario E. C.
Thomson, James E.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 792 : 66 - 73
[24] Influence of the electronic effects of phosphine ligands upon the properties of cyclopalladated complexes containing a σ(Pd-Csp2, ferrocene)bond -: X-Ray crystal structures of [Pd{(η5-C5H5)Fe[(η5-C5H3)C(Me)=N(C6H4-4-Me)]}Cl(PPh3)] and [Pd{(η5-C5H5)Fe[(η5-C5H3)CH2NMe2]}Cl(PPh3)]
Lopez, C
Bosque, R
Solans, X
Font-Bardia, M
NEW JOURNAL OF CHEMISTRY, 1998, 22 (09) : 977 - 982
[25] BIMETALLIC ORGANOTRANSITION-METAL TAUTOMERS OF A CHIRAL ENOLATE - PREPARATION OF [(ETA-5-C5H5)FE(CO)(PPH3)C(CH2)O(CL)ZR(ETA-5-C5H5)2] AND [(ETA-5-C5H5)FE(CO)(PPH3)C(O)CH2AU(PPH3)] - X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5H5)FE(CO)(PPH3)C(CH2)O(CL)ZR(ETA-5-C5H5)2]
WEINSTOCK, I
FLORIANI, C
CHIESIVILLA, A
GUASTINI, C
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (26) : 8298 - 8299
[26] Photochemical displacement of co-ordinated ethene from [Rh(η5-C5H5)(PPh3)(C2H4)]
Heaton, SN
Partridge, MG
Perutz, RN
Parsons, SJ
Zimmermann, F
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (15): : 2515 - 2520
[27] Syntheses　and　Characterizations　of　（η5－C5H5）MoFeCo（CO）8（μ3－S）　and　（η5－C5H5）2Mo2Fe（CO）7（μ3－S）：X－ray　Crystal　Structure　of　（η5－C5H5）MoFeCo（CO）8（μ3－S）
SUN Wen-Hua
WANG Han-Qing
TAN Wen-Fei
YANG Shi Yan (State Key Laboratory of Oxo Synthesis and Selective Oxidation
结构化学, 1996, (05) : 382 - 386
[28] (η5-C5H5)-Ring alkylation reaction with the C5H5 anion:: towards the construction of tri-Fe complex Fe{[μ,η5:η4-5-exo-(1′-C5H4)C5H5]Fe(CO)2(PPh3)}2
Luh, LS
Liu, LK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 : 549 - 557
[29] Synthesis, characterisation and some reactions of alkynyl derivatives [Ni(η5-C5H5)(PPh3)C=CX]
Gallagher, JF
Butler, P
Hudson, RDA
Manning, AR
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (01): : 75 - 82
[30] Trans-influences in mononuclear cyclopalladated compounds containing a σ(Pd-Csp2, ferrocene) bond.: X-ray crystal structures of [Pd{[(η5-C5H3)-CH=N-CH2-C6H5]Fe(η5-C5H5)}(X)(PPh3)] with X- = Br- and I-
Pérez, S
Bosque, R
López, C
Solans, X
Font-Bardia, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 625 (01) : 67 - 76

← 1 2 3 4 5 →