A novel copper containing photoinitiator, copper(II) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization

被引:66
作者
Gong, Tao [1 ]
Adzima, Brian J. [1 ]
Bowman, Christopher N. [1 ]
机构
[1] Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309 USA
基金
美国国家科学基金会;
关键词
AZIDE-ALKYNE CYCLOADDITION; TERMINAL ALKYNES; CLICK CHEMISTRY; LIGHT; PHOTOPOLYMERIZATION; OXIDE; ATRP;
D O I
10.1039/c3cc43637c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel copper(II) complex has been developed in which the counter anion, acylphosphinate, serves as a visible light photoinitiator. This molecule is inactive in the dark but, upon visible light exposure, both CuAAC and ATRP reactions are readily and rapidly initiated.
引用
收藏
页码:7950 / 7952
页数:3
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