Manipulation of mesoporous silica hollow spheres by control of silica precursors

被引:7
作者
Chen, Hao [1 ]
Yan, Zhuojun [1 ]
Li, Baozong [1 ]
Li, Yi [1 ]
Wu, Qi-Hui [2 ]
机构
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
[2] Quanzhou Normal Univ, Dept Chem, Coll Chem & Life Sci, Quanzhou 362000, Peoples R China
基金
中国国家自然科学基金;
关键词
Hollow sphere; Mesoporous silica; Porous materials; Sol-gel preparation; TEMPLATES;
D O I
10.1016/j.matlet.2013.09.040
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Mesoporous hollow nanospheres have attracted much attention due to their potential applications in the fields of catalysis and drug release. Recently, various hollow silica nanospheres with mesopores in the walls have been prepared through templating approaches. However, the effect of silica precursors on the hollow structure has not been well studied. Herein, mesoporous silica hollow nanospheres were prepared through a chiral amphiphile/organic solvent dual-templating approach. The silica nanostructures are controllable by manipulating the amount of the silica precursors. A diffusion-polycondensation mechanism was proposed to drive the formation of the hollow spheres. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:78 / 80
页数:3
相关论文
共 19 条
  • [1] Chemistry Caruso F., 2000, CHEM-EUR J, V6, P413
  • [2] Preparation of hollow silica spheres with holes on the shells
    Chen, Yuanli
    Li, Yi
    Chen, Yuxia
    Liu, Xiaojuan
    Zhang, Ming
    Li, Baozong
    Yang, Yonggang
    [J]. CHEMICAL COMMUNICATIONS, 2009, (34) : 5177 - 5179
  • [3] Handedness inversion in preparing mesoporous silica nanoribbons
    Chen, Yuanli
    Guo, Yongmin
    Zhao, Huanyu
    Bi, Lifeng
    Pei, Xianfeng
    Li, Baozong
    Yang, Yonggang
    [J]. NANOTECHNOLOGY, 2008, 19 (35)
  • [4] Gallis KW, 1999, ADV MATER, V11, P1452, DOI 10.1002/(SICI)1521-4095(199912)11:17<1452::AID-ADMA1452>3.0.CO
  • [5] 2-R
  • [6] Silica hollow spheres by templating of catanionic vesicles
    Hentze, HP
    Raghavan, SR
    McKelvey, CA
    Kaler, EW
    [J]. LANGMUIR, 2003, 19 (04) : 1069 - 1074
  • [7] Hubert DHW, 2000, ADV MATER, V12, P1291, DOI 10.1002/1521-4095(200009)12:17<1291::AID-ADMA1291>3.3.CO
  • [8] 2-Q
  • [9] MESOSTRUCTURE DESIGN WITH GEMINI SURFACTANTS - SUPERCAGE FORMATION IN A 3-DIMENSIONAL HEXAGONAL ARRAY
    HUO, QS
    LEON, R
    PETROFF, PM
    STUCKY, GD
    [J]. SCIENCE, 1995, 268 (5215) : 1324 - 1327
  • [10] Synthesis and characterization of hyperbranched mesoporous silica SBA-15
    Kónya, Z
    Zhu, J
    Szegedi, A
    Kiricsi, I
    Alivisatos, P
    Somorjai, GA
    [J]. CHEMICAL COMMUNICATIONS, 2003, (03) : 314 - 315