Synthesis of Single-Walled Carbon Nanotubes: Effects of Active Metals, Catalyst Supports, and Metal Loading Percentage

被引:19
作者
Liu, Wei-Wen [1 ,2 ]
Aziz, Azizan [2 ]
Chai, Siang-Piao [3 ]
Mohamed, Abdul Rahman [4 ]
Hashim, U. [1 ]
机构
[1] Univ Malaysia Perlis, INEE, Kangar 01000, Perlis, Malaysia
[2] Univ Sains Malaysia, Sch Mat & Mineral Resources Engn, Nibong Tebal 14300, Pulau Pinang, Malaysia
[3] Monash Univ, Sch Engn, Bandar Sunway 46150, Selangor, Malaysia
[4] Univ Sains Malaysia, Sch Chem Engn, Nibong Tebal 14300, Pulau Pinang, Malaysia
关键词
CHEMICAL-VAPOR-DEPOSITION; CVD SYNTHESIS; FE/MGO-CATALYST; GROWTH; NANOPARTICLES; QUALITY; PARTICLES; MECHANISM; ALUMINA; METHANE;
D O I
10.1155/2013/592464
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effects of active metals, catalyst supports, and metal loading percentage on the formation of single-walled carbon nanotubes (SWNTs) were studied. In particular, iron, cobalt, and nickel were investigated for SWNTs synthesis. Iron was found to grow better-quality SWNTs compared to cobalt and nickel. To study the effect of catalyst supports, magnesium oxide, silicon oxide, and aluminium oxide were chosen for iron. Among the studied supports, MgO was identified to be a suitable support for iron as it produced SWNTs with better graphitisation determined by Raman analysis. Increasing the iron loading decreased the quality of SWNTs due to extensive agglomeration of the iron particles. Thus, lower metal loading percentage is preferred to grow better-quality SWNTs with uniform diameters.
引用
收藏
页数:8
相关论文
共 51 条
  • [1] CVD growth of single-walled carbon nanotubes with narrow diameter distribution over Fe/MgO catalyst and their fluorescence spectroscopy
    Ago, H
    Imamura, S
    Okazaki, T
    Saitoj, T
    Yumura, M
    Tsuji, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (20) : 10035 - 10041
  • [2] Roles of metal-support interaction in growth of single- and double-walled carbon nanotubes studied with diameter-controlled iron particles supported on MgO
    Ago, H
    Nakamura, K
    Uehara, N
    Tsuji, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (49) : 18908 - 18915
  • [3] Growth of double-wall carbon nanotubes with diameter-controlled iron oxide nanoparticles supported on MgO
    Ago, H
    Nakamura, K
    Imamura, S
    Tsuji, M
    [J]. CHEMICAL PHYSICS LETTERS, 2004, 391 (4-6) : 308 - 313
  • [4] Multiwall carbon nanotubes: Synthesis and application
    Andrews, R
    Jacques, D
    Qian, DL
    Rantell, T
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (12) : 1008 - 1017
  • [5] CVD synthesis of single-walled carbon nanotubes from gold nanoparticle catalysts
    Bhaviripudi, Sreekar
    Mile, Ervin
    Steiner, Stephen A., III
    Zare, Aurea T.
    Dresselhaus, Mildred S.
    Belcher, Angela M.
    Kong, Jing
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (06) : 1516 - +
  • [6] Selective growth of carbon nantoubes on SiO2/Si substrate
    Cao, J. M.
    [J]. APPLIED SURFACE SCIENCE, 2006, 253 (05) : 2460 - 2464
  • [7] Synthesis of high purity narrow-width carbon nanotubes
    Carneiro, O. C.
    Anderson, P. E.
    Rodriguez, N. M.
    Baker, R. T. K.
    [J]. CARBON, 2012, 50 (09) : 3200 - 3209
  • [8] Cassell AM, 1999, J PHYS CHEM B, V103, P6484, DOI 10.1021/jp990957sCCC:$18.00
  • [9] Fluidized bed catalytic chemical vapor deposition synthesis of carbon nanotubes-A review
    Danafar, Firoozeh
    Fakhru'l-Razi, A.
    Salleh, Mohd Amran Mohd
    Biak, Dayang Radiah Awang
    [J]. CHEMICAL ENGINEERING JOURNAL, 2009, 155 (1-2) : 37 - 48
  • [10] Platelet-like catalyst design for high yield production of multi-walled carbon nanotubes by catalytic chemical vapor deposition
    David Nunez, J.
    Maser, Wolfgang K.
    Mayoral, M. Carmen
    Andres, Jose M.
    Benito, Ana M.
    [J]. CARBON, 2011, 49 (07) : 2483 - 2491