Synthesis and reactivity of cyclopentadienyl iron complexes containing ferrocenyl selenolates

被引：10

作者：

Taher, Deeb ^{[1
]}

Awwadi, Firas ^{[1
]}

El-khateeb, Mohammad ^{[2
,3
]}

Lang, Heinrich ^{[4
]}

机构：

[1] Univ Jordan, Dept Chem, Amman 11942, Jordan

[2] King Abdulaziz Univ, Dept Chem, Fac Sci & Arts Alkamil Prov, Alkamil 21931, Saudi Arabia

[3] Jordan Univ Sci & Technol, Dept Chem, Irbid 22110, Jordan

[4] Tech Univ Chemnitz, Lehrstuhl Anorgan Chem, Inst Chem, D-09111 Chemnitz, Germany

来源：

TRANSITION METAL CHEMISTRY | 2012年 / 37卷 / 06期

关键词：

LIGANDS; CRYSTAL; DERIVATIVES; RUTHENIUM; CATALYSIS; BRIDGES; SURFACE; SERIES;

D O I：

10.1007/s11243-012-9628-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New homo-trimetallic complexes of general formula 1,1 '-fc[SeFeCp(CO)(2)](2) (fc = Fe(eta(5)-C5H4)(2)) are accessible in high yield by the reaction of 1,1 '-fc(SeLi)(2), which is generated from 1,1 '-fc(SeSiMe3)(2) and n-BuLi, with two equivalents of CpFe(CO)(2)I. Photolytic CO-substitution reactions of the organoiron diselenolate with bis-phosphines at -50 degrees C using 1:2 (metal/ligand) molar ratio afforded 1,1 '-fc(SeFeCp(P boolean AND P)(2). All these complexes were characterized by physicochemical and spectroscopic methods.

引用

页码：601 / 604

页数：4

共 33 条

[1] PREPARATION OF NOVEL PLATINUM AND PALLADIUM COMPLEXES BY REACTION OF 1,1'-METALLOCENEDICHALCOGENOLS WITH TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0) OR TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0) - THE IMPORTANT ROLE OF THE COORDINATING ABILITY OF THE METAL ATOM OF THE METALLOCENE IN PRODUCT FORMATIONH [J].