Recent Progress of Cu-Based Catalysts for Catalytic Elimination of CO

被引:11
作者
Yu Qiang [1 ]
Gao Fei [2 ]
Dong Lin [1 ,2 ]
机构
[1] Nanjing Univ, Sch Chem & Chem Engn, MOE, Key Lab Mesoscop Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Ctr Modern Anal, Jiangsu Key Lab Vehicle Emiss Control, Nanjing 210093, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon monoxide; complete oxidation; preferential oxidation; Cu-based catalyst; GAS SHIFT REACTION; PREFERENTIAL OXIDATION; SELECTIVE OXIDATION; LOW-TEMPERATURE; CUO-CEO2; CATALYSTS; EXCESS HYDROGEN; CARBON-MONOXIDE; ACTIVE-SITES; H-2-RICH STREAM; OXIDE CATALYSTS;
D O I
10.3724/SP.J.1088.2012.20401
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Catalytic elimination of CO mainly includes complete oxidation (CO-COOX) and preferential oxidation of CO (CO-PROX). First, combined with our group's research, a brief introduction to the active species and the interaction between components in Cu-based catalysts for CO-COOX was presented from the perspective of the catalyst system. Then recent progress in CO-PROX under H-2-rich over Cu-based catalysts was systematically summarized. Influence of the preparation method, promoter, and support of CuO-CeO2 catalyst as well as transition metal ions doped support (CuO/Ce1-xMxO2), and inverse structure (CeO2/CuO) on the catalytic performance in CO-PROX was elaborated. Finally, the application problems and future research trend of Cu-based catalysts for catalytic removal of CO were discussed and summarized.
引用
收藏
页码:1245 / 1256
页数:12
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