A new family of lanthanide-based coordination polymers with azoxybenzene-3,3′,5,5′-tetracarboxylic acid as ligand

被引：5

作者：

Wang, Jinzeng ^{[1
]}

Daiguebonne, Carole ^{[1
]}

Suffren, Yan ^{[1
]}

Roisnel, Thierry ^{[1
]}

Freslon, Stephane ^{[1
]}

Calvez, Guillaume ^{[1
]}

Bernot, Kevin ^{[1
]}

Guillou, Olivier ^{[1
]}

机构：

[1] Univ Rennes, INSA Rennes, CNRS, Inst Sci Chim Rennes,UMR 6226, F-35708 Rennes, France

来源：

INORGANICA CHIMICA ACTA | 2019年 / 488卷

关键词：

Lanthanide coordination polymers; Crystal structure; Luminescent properties; Azoxybenzene-,3,3 ',5,5 '-tetracarboxylic acid; Thermal analysis; METAL-ORGANIC FRAMEWORKS; ENERGY-TRANSFER; LUMINESCENCE; EMISSION; BRIGHTNESS; COMPLEXES; MODULATION; SCIENCE;

D O I：

10.1016/j.ica.2019.01.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions by solvothermal methods of lanthanide nitrates and azoxybenzene-3,3',5,5'-tetracarboxylic acid (H(4)aobtc) lead to a family of isostructural lanthanide-based coordination polymers with general chemical formula [Ln(Haobtc)(H2O)(2)center dot 2H(2)O](infinity) with Ln = Nd - Er plus Y. The crystal structure has been solved on the basis of the Y3+ -derivative. It crystallizes in the triclinic system, space group P-1 (no2) with the following cell parameters: a = 6.6890(18) angstrom, b = 10.052(3) angstrom, c = 13.879(4) angstrom,alpha = 75.756(9)degrees, beta = 77.551(9)degrees, gamma = 83.964(9)degrees and Z = 2. The crystal structure is two-dimensional (2D). Thermal properties and luminescent properties of the Nd3+-containing compound have been studied.

引用

页码：208 / 213

页数：6

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