Aggregation of CO2 and Organic Liquid Molecules at Near Critical and Supercritical Condition of CO2

被引：5

作者：

Yang, Zihao ^{[1
]}

Li, Mingyuan ^{[1
,2
]}

Peng, Bo ^{[1
,3
]}

Lin, Meiqin ^{[1
,3
]}

Dong, Zhaoxia ^{[1
]}

机构：

[1] China Univ Petr, Enhanced Oil Recovery Res Inst, Beijing 102249, Peoples R China

[2] State Key Lab Heavy Oil Proc, Beijing, Peoples R China

[3] CNPC, Key Lab Enhanced Oil Recovery, Beijing, Peoples R China

来源：

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY | 2014年 / 35卷 / 02期

关键词：

Carbon dioxide; dispersion property; molecular dynamic simulation; molecule aggregation; FLUID-PHASE-EQUILIBRIA; CARBON-DIOXIDE; VOLUME EXPANSION; DISPERSION PROPERTY; RAPID EXPANSION; SYSTEMS; BINARY; ANTISOLVENT; MIXTURES;

D O I：

10.1080/01932691.2013.778781

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In order to study the aggregation of CO2 and organic liquid molecules in the binary systems of CO2+ organic liquid at near critical and supercritical condition of CO2, the radial distribution function of CO2-organic liquid molecules and organic liquid-organic liquid molecules in the liquid phase of the CO2+ organic liquid systems is calculated by molecular dynamic simulation in this work and compared with the results of our previous works. The results of the research show that the aggregates of CO2-CO2 molecules, CO2-organic liquid molecules and organic liquid-organic liquid molecules are coexisted in the liquid phase of CO2+ organic liquid system, respectively.

引用

页码：168 / 174

页数：7

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