Solution-processed bi-layer polythiophene-fullerene organic solar cells

被引：8

作者：

Ghoos, Toon ^{[1
]}

Malinkiewicz, Olga ^{[2
]}

Conings, Bert ^{[3
]}

Lutsen, Laurence ^{[1
,4
]}

Vanderzande, Dirk J. ^{[1
,4
]}

Bolink, Henk J. ^{[2
]}

Maes, Wouter ^{[1
,4
]}

机构：

[1] Hasselt Univ, Inst Mat Res IMO IMOMEC, B-3590 Diepenbeek, Belgium

[2] Univ Valencia, Inst Ciencia Mol, ES-46980 Valencia, Spain

[3] Hasselt Univ, Inst Mat Res IMO IMOMEC, Nanostruct Phys NSP, B-3590 Diepenbeek, Belgium

[4] IMEC, IMOMEC Assoc Lab, B-3590 Diepenbeek, Belgium

来源：

RSC ADVANCES | 2013年 / 3卷 / 47期

关键词：

FUNCTIONALIZED POLY(3-ALKYLTHIOPHENE) COPOLYMERS; PHOTOVOLTAIC DEVICES; QUANTUM EFFICIENCY; POLYELECTROLYTE; PERFORMANCE; STABILITY; P3HT/PCBM; DESIGN;

D O I：

10.1039/c3ra43986k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An ionic polymer based on a polythiophene backbone with appended imidazolium moieties was successfully implemented as a donor material in fully solution-processed efficient bi-layer solar cells prepared by the low impact meniscus coating technique. High fill factors and device reproducibility were obtained, even for ultrathin polymer layers, indicating excellent film formation properties and good compatibility with solution processing techniques. The possibility of smooth counter ion exchange, allowing solubility modification and efficiency tuning, enables exploration of new functionalities and other device architectures.

引用

页码：25197 / 25203

页数：7

共 53 条

[1] THIOPHENES .1. FACILE SYNTHESIS OF 3-(OMEGA-HALOALKYL)THIOPHENES AS KEY BUILDING-BLOCKS FOR FUNCTIONALIZED THIOPHENES AND POLYTHIOPHENES [J].

BAUERLE, P ;

WURTHNER, F ;

HEID, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1990, 29 (04) :419-420

[2] Ionic space charge driven organic photovoltaic devices [J].

Benmansour, Hadjar ;

Castro, Fernando A. ;

Nagel, Matthias ;

Heier, Jakob ;

Hany, Roland ;

Nueesch, Frank .

CHIMIA, 2007, 61 (12) :787-791

[3] Improved thermal stability of bulk heterojunctions based on side-chain functionalized poly(3-alkylthiophene) copolymers and PCBM [J].

Bertho, Sabine ;

Campo, Bert ;

Piersimoni, Fortunato ;

Spoltore, Donato ;

D'Haen, Jan ;

Lutsen, Laurence ;

Maes, Wouter ;

Vanderzande, Dirk ;

Manca, Jean .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2013, 110 :69-76

[4] Synthesis and Properties of Cationic Polyelectrolyte with Regioregular Polyalkylthiophene Backbone and Ionic-Liquid Like Side Groups [J].

Bondarev, Dmitrij ;

Zednik, Jiri ;

Sloufova, Ivana ;

Sharf, Ahmed ;

Prochazka, Marek ;

Pfleger, Jiri ;

Vohlidal, Jiri .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (14) :3073-3081

[5] Accounting for Interference, Scattering, and Electrode Absorption to Make Accurate Internal Quantum Efficiency Measurements in Organic and Other Thin Solar Cells [J].

Burkhard, George F. ;

Hoke, Eric T. ;

McGehee, Michael D. .

ADVANCED MATERIALS, 2010, 22 (30) :3293-+

[6] Ester-functionalized poly(3-alkylthiophene) copolymers: Synthesis, physicochemical characterization and performance in bulk heterojunction organic solar cells [J].

Campo, Bert J. ;

Bevk, David ;

Kesters, Jurgen ;

Gilot, Jan ;

Bolink, Henk J. ;

Zhao, Jun ;

Bolsee, Jean-Christophe ;

Oosterbaan, Wibren D. ;

Bertho, Sabine ;

D'Haen, Jan ;

Manca, Jean ;

Lutsen, Laurence ;

Van Assche, Guy ;

Maes, Wouter ;

Janssen, Rene A. J. ;

Vanderzande, Dirk .

ORGANIC ELECTRONICS, 2013, 14 (02) :523-534

[7] Improved performance of cyanine solar cells with polyaniline anodes [J].

Fan, Bin ;

de Castro, Fernando Araujo ;

Chu, Bryan Tsu-Te ;

Heier, Jakob ;

Opris, Dorina ;

Hany, Roland ;

Nueesch, Frank .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (15) :2952-2955

[8] Nongeminate Recombination in Planar and Bulk Heterojunction Organic Solar Cells [J].

Foertig, Alexander ;

Wagenpfahl, Alexander ;

Gerbich, Thiemo ;

Cheyns, David ;

Dyakonov, Vladimir ;

Deibel, Carsten .

ADVANCED ENERGY MATERIALS, 2012, 2 (12) :1483-1489

[9] Discriminating between Bilayer and Bulk Heterojunction Polymer: Fullerene Solar Cells Using the External Quantum Efficiency [J].

Gevaerts, Veronique S. ;

Koster, L. Jan Anton ;

Wienk, Martijn M. ;

Janssen, Rene A. J. .

ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (09) :3252-3255

[10]

Ghoos T., POLYMER, DOI [10.1016/j.polymer.2013.09.049, DOI 10.1016/J.P0LYMER.2013.09.049]

← 1 2 3 4 5 6 →