Mo-Si-Al-C multiphase oxidation protective coating for carbon/carbon composites

被引:21
作者
Li, Ting [1 ]
Li, Hejun [1 ]
Shi, Xiaohong [1 ]
Cheng, Jing [1 ]
Liu, Lei [1 ]
机构
[1] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Carbon Carbon Composites Res Ctr, Xian 710072, Shaanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon/carbon composites; Mo-Si-Al-C multiphase coating; Oxidation; HIGH-TEMPERATURE OXIDATION; X INTERMETALLICS X=AL; BEHAVIOR; TA; ZR; TI;
D O I
10.1016/j.apsusc.2013.03.050
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A multiphase coating based on Mo-Si-Al-C was formed on the surface of carbon/carbon (C/C) composites by a two-step pack cementation technique in argon atmosphere. Microstructure of the multiphase coating was characterized by X-ray diffraction, scanning electron microscope and energy dispersive spectroscope. X-ray diffraction analysis showed that the multiphase coating was composed of SiC, Mo (Si, Al)(2), MoSi2 and Al4Mo3Si2. The multiphase coating coated C/C composites exhibited a weight loss of only 0.409% after oxidation in air at 1773 K for 510 h and could endure thermal cycling between 1773 K and room temperature for 25 times. The weight loss of the coated C/C composites was primarily due to the reaction between C/C matrix and oxygen. (C) 2013 Published by Elsevier B.V.
引用
收藏
页码:154 / 158
页数:5
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