Perovskite chemical gardens: highly fluorescent microtubes from self-assembly and ion exchange

被引:9
作者
Batista, Bruno C. [1 ]
Steinbock, Oliver [1 ]
机构
[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
关键词
CALCIUM-CARBONATE; PB(II); CACO3;
D O I
10.1039/d2cc05611a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the shape-preserving conversion of self-assembled CaCO3 microtubes to PbCO3 and MAPbBr(3) perovskite. The first step induces the growth of cerussite needles on the outer surface. When further converted, these hedgehog-like structures become fluorescent. Additional spatial control of the process yields Janus tubes of CaCO3 and perovskite segments.
引用
收藏
页码:12736 / 12739
页数:4
相关论文
共 41 条
[1]   Emergent Behavior at the Calcite-Water Interface during Reactive Transport in a Simple Microfluidic Channel [J].
Abdilla, Bektur ;
Minahan, Daniel J. ;
Gleghorn, Jason P. ;
Kim, YoungJae ;
Lee, Sang Soo ;
Fenter, Paul ;
Sturchio, Neil C. .
ACS EARTH AND SPACE CHEMISTRY, 2022, 6 (04) :861-870
[2]   Extreme strength observed in limpet teeth [J].
Barber, Asa H. ;
Lu, Dun ;
Pugno, Nicola M. .
JOURNAL OF THE ROYAL SOCIETY INTERFACE, 2015, 12 (105)
[3]   From Chemical Gardens to Chemobrionics [J].
Barge, Laura M. ;
Cardoso, Silvana S. S. ;
Cartwright, Julyan H. E. ;
Cooper, Geoffrey J. T. ;
Cronin, Leroy ;
De Wit, Anne ;
Doloboff, Ivria J. ;
Escribano, Bruno ;
Goldstein, Raymond E. ;
Haudin, Florence ;
Jones, David E. H. ;
Mackay, Alan L. ;
Maselko, Jerzy ;
Pagano, Jason J. ;
Pantaleone, J. ;
Russell, Michael J. ;
Ignacio Sainz-Diaz, C. ;
Steinbock, Oliver ;
Stone, David A. ;
Tanimoto, Yoshifumi ;
Thomas, Noreen L. .
CHEMICAL REVIEWS, 2015, 115 (16) :8652-8703
[4]   Chemical gardens without silica: the formation of pure metal hydroxide tubes [J].
Batista, Bruno C. ;
Steinbock, Oliver .
CHEMICAL COMMUNICATIONS, 2015, 51 (65) :12962-12965
[5]   Morphogenesis of polyoxometalate cluster-based materials to microtubular network architectures [J].
Boulay, Antoine G. ;
Cooper, Geoffrey J. T. ;
Cronin, Leroy .
CHEMICAL COMMUNICATIONS, 2012, 48 (42) :5088-5090
[6]   INFRARED AND RAMAN-SPECTRA AND X-RAY-DIFFRACTION STUDIES OF SOLID LEAD(II) CARBONATES [J].
BROOKER, MH ;
SUNDER, S ;
TAYLOR, P ;
LOPATA, VJ .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1983, 61 (03) :494-502
[7]   Carbonate-hydroxide chemical-garden tubes in the soda ocean of Enceladus: Abiotic membranes and microtubular forms of calcium carbonate [J].
Cardoso, Silvana S. S. ;
Cartwright, Julyan H. E. ;
Ignacio Sainz-Diaz, C. .
ICARUS, 2019, 319 :337-348
[8]   Fluid-flow-templated self-assembly of calcium carbonate tubes in the laboratory and in biomineralization: The tubules of the watering-pot shells, Clavagelloidea [J].
Cardoso, Silvana S. S. ;
Cartwright, Julyan H. E. ;
Checa, Antonio G. ;
Sinz-Diaz, C. Ignacio .
ACTA BIOMATERIALIA, 2016, 43 :338-347
[9]   Synthesis of CaCO3 nano- and micro-particles by dry ice carbonation [J].
Donnelly, F. C. ;
Purcell-Milton, F. ;
Framont, V. ;
Cleary, O. ;
Dunne, P. W. ;
Gun'ko, Y. K. .
CHEMICAL COMMUNICATIONS, 2017, 53 (49) :6657-6660
[10]  
Dou L., 2017, P NATL ACAD SCI USA, V140