Tetrel-Bonding Interaction: Rediscovered Supramolecular Force?

被引：532
|
作者：
Bauza, Antonio [1 ]
Mooibroek, Tiddo J. [2 ]
Frontera, Antonio [1 ]
机构：
[1] Univ Illes Balears, Dept Quim, Palma De Mallorca 07122, Baleares, Spain
[2] Univ Bristol, Sch Chem, Bristol, Avon, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 47期
关键词：
ab initio calculations; group; 14; elements; noncovalent interactions; silicon; supramolecular chemistry; BETA-DONOR BONDS; CRYSTAL-STRUCTURE; HYDROGEN;
D O I：
10.1002/anie.201306501
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The w(hole) picture: A tetrel bond is a directional noncovalent interaction between a covalently bonded atom of Group IV and a negative site, for example, the lone pair of a Lewis base or an anion. It involves a region of positive electrostatic potential (σ hole), and energetically, they are comparable to hydrogen bonds and other σ-hole-based interactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12317 / 12321
页数：5
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