Tetrel-Bonding Interaction: Rediscovered Supramolecular Force?

被引：532

作者：

Bauza, Antonio ^{[1
]}

Mooibroek, Tiddo J. ^{[2
]}

Frontera, Antonio ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Palma De Mallorca 07122, Baleares, Spain

[2] Univ Bristol, Sch Chem, Bristol, Avon, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 47期

关键词：

ab initio calculations; group; 14; elements; noncovalent interactions; silicon; supramolecular chemistry; BETA-DONOR BONDS; CRYSTAL-STRUCTURE; HYDROGEN;

D O I：

10.1002/anie.201306501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The w(hole) picture: A tetrel bond is a directional noncovalent interaction between a covalently bonded atom of Group IV and a negative site, for example, the lone pair of a Lewis base or an anion. It involves a region of positive electrostatic potential (σ hole), and energetically, they are comparable to hydrogen bonds and other σ-hole-based interactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12317 / 12321

页数：5