Piezoelectric response of nanoscale PbTiO3 in composite PbTiO3-CoFe2O4 epitaxial films

被引:17
作者
Tan, Zhuopeng [1 ]
Roytburd, Alexander L. [1 ]
Levin, Igor [2 ]
Seal, Katyayani [3 ]
Rodriguez, Brian J. [3 ]
Jesse, Stephen [3 ]
Kalinin, Sergei [3 ]
Baddorf, Art [3 ]
机构
[1] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA
[2] Natl Inst Stand & Technol, Div Ceram, Gaithersburg, MD 20899 USA
[3] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA
关键词
D O I
10.1063/1.2969038
中图分类号
O59 [应用物理学];
学科分类号
摘要
Piezoelectric properties of PbTiO3 in 1/3PbTiO(3)-2/3CoFe(2)O(4) transverse epitaxial nanostructures on differently oriented SrTiO3 were analyzed using conventional and switching-spectroscopy piezoelectric force microscopy. The results confirmed that the individual PbTiO3 nanocolumns in the CoFe2O4 matrix exhibit a detectable piezoelectric response regardless of substrate orientation. For the {100} and {110} orientations, a bias of +/- 10 V produced ferroelectric domain switching; however, no switching was observed for the {111} films. Small values of piezoelectric constants d(zz)((100))approximate to 11 pm/V, d(zz)((110))approximate to 5 pm/V, and d(zz)((111))approximate to 3pm/V are attributed to the weak intrinsic response of the nano-PbTiO3 under strong mechanical and depolarizing-field constraints in the composite films. (c) 2008 American Institute of Physics.
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页数:3
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