Piezoelectric properties of PbTiO3 in 1/3PbTiO(3)-2/3CoFe(2)O(4) transverse epitaxial nanostructures on differently oriented SrTiO3 were analyzed using conventional and switching-spectroscopy piezoelectric force microscopy. The results confirmed that the individual PbTiO3 nanocolumns in the CoFe2O4 matrix exhibit a detectable piezoelectric response regardless of substrate orientation. For the {100} and {110} orientations, a bias of +/- 10 V produced ferroelectric domain switching; however, no switching was observed for the {111} films. Small values of piezoelectric constants d(zz)((100))approximate to 11 pm/V, d(zz)((110))approximate to 5 pm/V, and d(zz)((111))approximate to 3pm/V are attributed to the weak intrinsic response of the nano-PbTiO3 under strong mechanical and depolarizing-field constraints in the composite films. (c) 2008 American Institute of Physics.
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Oak Ridge Natl Lab, Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USAOak Ridge Natl Lab, Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USA
Kalinin, Sergei V.
Rar, Andrei
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机构:Oak Ridge Natl Lab, Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USA
Rar, Andrei
Jesse, Stephen
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机构:Oak Ridge Natl Lab, Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USA
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Univ Maryland, Dept Mat Sci & Engn, Mat Res & Sci Engn Ctr, College Pk, MD 20742 USAUniv Maryland, Dept Mat Sci & Engn, Mat Res & Sci Engn Ctr, College Pk, MD 20742 USA
Ouyang, J
Ramesh, R
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Ramesh, R
Roytburd, AL
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Oak Ridge Natl Lab, Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USAOak Ridge Natl Lab, Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USA
Kalinin, Sergei V.
Rar, Andrei
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机构:Oak Ridge Natl Lab, Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USA
Rar, Andrei
Jesse, Stephen
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机构:Oak Ridge Natl Lab, Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USA
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Univ Maryland, Dept Mat Sci & Engn, Mat Res & Sci Engn Ctr, College Pk, MD 20742 USAUniv Maryland, Dept Mat Sci & Engn, Mat Res & Sci Engn Ctr, College Pk, MD 20742 USA
Ouyang, J
Ramesh, R
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机构:Univ Maryland, Dept Mat Sci & Engn, Mat Res & Sci Engn Ctr, College Pk, MD 20742 USA
Ramesh, R
Roytburd, AL
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机构:Univ Maryland, Dept Mat Sci & Engn, Mat Res & Sci Engn Ctr, College Pk, MD 20742 USA