Synthesis of a ruthenium complex of a cyclic trifunctional η6, η1, η1-arene-diphosphine ligand by intramolecular dehydrofluorinative carbon-carbon coupling

被引：21

作者：

Bellabarba, RM ^{[1
]}

Saunders, GC ^{[1
]}

Scott, S ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

ruthenium; eta(6)-arene; phosphine; dehydrofluorinative carbon-carbon coupling; hybrid ligands;

D O I：

10.1016/S1387-7003(01)00339-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the ruthenium complex cation [(eta(6)-C6H3Me3-1,3,5)(RuCl(dfppe)](+) {dfppe = (C6F5)(2)PCH2CH2P(C6F5)(2)} with proton sponge yields [{eta(6).eta(1).eta(1) -C6H3Me-5-[CH2-2-C6F4P(C6F5)CH2](2)-1,3}RuCl](+). by stepwise intramolecular dehydrofluorinative carbon-carbon coupling. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：15 / 18

页数：4

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