White-emitting carbon dots with long alkyl-chain structure: Effective inhibition of aggregation caused quenching effect for label-free imaging of latent fingerprint

被引：135

作者：

Jiang, Bang-Ping ^{[1
]}

Yu, Yun-Xiang ^{[1
]}

Guo, Xiao-Lu ^{[1
]}

Ding, Zhao-Yang ^{[1
]}

Zhou, Bo ^{[1
]}

Liang, Hong ^{[1
]}

Shen, Xing-Can ^{[1
]}

机构：

[1] Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, Key Lab Chem & Mol Engn Med Resources, Guilin 541004, Peoples R China

来源：

CARBON | 2018年 / 128卷

关键词：

GRAPHENE QUANTUM DOTS; INDUCED EMISSION; ONE-STEP; NANODOTS; PHOTOLUMINESCENCE; STATE; RECOGNITION; PYROLYSIS; HYBRIDS; GREEN;

D O I：

10.1016/j.carbon.2017.11.070

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The surface functionalization of carbon dots (CDs) can introduce an additional dimension for the control of their photoluminescence properties and effective promotion of the applications of CDs such as imaging, sensing, etc. In this study, a simple one-step carbonization using Tween 80 as the sole carbon source is described for directly synthesizing white-emitting CDs (WCDs) in high yield. The results revealed the presence of several long alkyl chains on the surface of the as-fabricated WCDs, which effectively suppress the aggregation-caused quenching (ACQ) effect and emit bright white luminescence under an UV illumination of 365 nm in the solution and solid states. Besides, together with the surface protection of long alkyl chains, WCDs preferentially interact with lipophilic fatty residues and are beneficial for the label-free imaging of latent fingerprints. This study provides a promising new method to not only effectively inhibit the intrinsic ACQ effect of CDs but also develop the surface engineering of functionalized white-emitting CDs for practical applications via facile synthesis. (c) 2017 Elsevier Ltd. All rights reserved.

引用

页码：12 / 20

页数：9

共 68 条

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