Preparation of a chiral Pt12 tetrahedral cage and its use in catalytic Michael addition reaction

被引：28

作者：

Bhat, Imtiyaz Ahmad ^{[1
]}

Devaraj, Aanthonisamy ^{[1
]}

Howlader, Prodip ^{[1
]}

Chi, Ki-Whan ^{[2
]}

Mukherjee, Partha Sarathi ^{[1
]}

机构：

[1] Indian Inst Sci, Inorgan & Phys Chem Dept, Bangalore 560012, Karnataka, India

[2] Univ Ulsan, Dept Chem, Ulsan 680749, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 38期

基金：

新加坡国家研究基金会;

关键词：

HOST-GUEST; SUPRAMOLECULAR CLUSTER; MOLECULAR RECOGNITION; SYNTHETIC RECEPTOR; DIELS-ALDER; ENCAPSULATION; COMPLEXES; INDOLES; WATER; STABILIZATION;

D O I：

10.1039/c8cc01487f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of chiral cis-[(1S,2S)-dch] Pt(NO3)(2) (M) [where (1S,2S)-dch = (1S,2S)-1,2-diaminocyclohexane] with a hexadentate ligand (L) in 3 : 1 stoichiometric ratio yielded a [12+4] self-assembled chiral M12L4 molecular tetrahedron (T). The cage T features an internal 3D nanocavity with large open 'windows', enabling it to catalyze Michael addition reactions of a series of nitrostyrene derivatives with indole in a 9 : 1 water : methanol mixture.

引用

页码：4814 / 4817

页数：4

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