Continuous Flow Organocatalytic C-H Functionalization and Cross-Dehydrogenative Coupling Reactions: Visible Light Organophotocatalysis for Multicomponent Reactions and C-C, C-P Bond Formations

被引：182

作者：

Rueping, Magnus ^{[1
]}

Vila, Carlos ^{[1
]}

Bootwicha, Teerawut ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

ACS CATALYSIS | 2013年 / 3卷 / 07期

关键词：

Photocatalysis; Sustainable Catalysis; Organocatalysis; Photoreactor; Rose Bengal; PHOTOREDOX CATALYSIS; AEROBIC OXIDATION; FORMING REACTIONS; AMINO RADICALS; DUAL CATALYSIS; ROSE-BENGAL; PHOTOCATALYSIS; CYCLOADDITIONS; EFFICIENT; ACIDS;

D O I：

10.1021/cs400350j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A continuous flow procedure for the efficient metal-free, visible light photoredox-catalyzed alpha-functionalization of tertiary amines has been developed. Rose Bengal has been identified as an effective organic photocatalyst for continuous flow C-C and C-P bond formations as well as multicomponent reactions.

引用

页码：1676 / 1680

页数：5

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