A 3D hybrid network containing large spherical cavities formed through a combination of metal coordination and hydrogen bonding

被引：129

作者：

García-Zarracino, R ^{[1
]}

Höpfl, H ^{[1
]}

机构：

[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca 62210, Morelos, Mexico

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 12期

关键词：

carboxylate ligands; host-guest systems; self-assembly; supramolecular chemistry; tin;

D O I：

10.1002/anie.200352862

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hole story: A microporous material with cavities that have an internal volume of 1850 Å3 has been formed from simple starting materials by combining them first through covalent coordination, and then through hydrogen-bonding interactions. The capsules in the 3D network can function as hosts for guest molecules such as triphenylmethane, sodium tetraphenylborate, and triptycene (see picture).

引用

页码：1507 / 1511

页数：5

共 38 条

[1] Crystal engineering of hydrogen-bonded assemblies -: A progress report [J].

Aakeröy, CB ;

Beatty, AM .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2001, 54 (07) :409-+

[2]

[Anonymous], SMART BRUK MOL AN RE

[3]

[Anonymous], 1996, CAMERON

[4] Hydrogen-bonded molecular capsules are stable in polar media [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

CHEMICAL COMMUNICATIONS, 2001, (22) :2376-2377

[5] Hydrogen bonded networks of coordination complexes [J].

Beatty, AM .

CRYSTENGCOMM, 2001, (51)

[6] Crystal engineering and organometallic architecture [J].

Braga, D ;

Grepioni, F ;

Desiraju, GR .

CHEMICAL REVIEWS, 1998, 98 (04) :1375-1405

[7]

BRAGA D, 2000, DALTON T, P3705

[8]

*BRUK AN XRAY SYST, 2001, SAINT NT VERS 6 04

[9]

*BRUK AN XRAY SYST, 2000, SHELXTL NT VERS 6 10

[10] MULTIDIMENSIONAL CRYSTAL ENGINEERING OF BIFUNCTIONAL METAL-COMPLEXES CONTAINING COMPLEMENTARY TRIPLE HYDROGEN-BONDS [J].

BURROWS, AD ;

CHAN, CW ;

CHOWDHRY, MM ;

MCGRADY, JE ;

MINGOS, DMP .

CHEMICAL SOCIETY REVIEWS, 1995, 24 (05) :329-&

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