Polychlorinated dibenzo-p-dioxins and dibenzofurans formed from sucralose at high temperatures

被引:17
|
作者
Dong, Shujun [1 ]
Liu, Guorui [1 ]
Hu, Jicheng [1 ]
Zheng, Minghui [1 ]
机构
[1] Chinese Acad Sci, State Key Lab Environm Chem & Ecotoxicol, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China
来源
SCIENTIFIC REPORTS | 2013年 / 3卷
基金
中国国家自然科学基金;
关键词
DE-NOVO SYNTHESIS; CHLORINE; FATE; PCDD;
D O I
10.1038/srep02946
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Sucralose is a widely-used artificial high-intensity sweetener. Although doubts have been raised about the safety of sucralose by several researchers, it can still be found in a broad range of foods and beverages worldwide, including in baked goods. Sucralose may decompose at high temperatures, and participate in chlorination reactions, generating highly toxic compounds. Here, we demonstrate that heating sucralose at high temperatures in stainless steel or other metal utensils in the presence of rust (Al2O3, Fe2O3, and CuO) produces polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). PCDD/Fs were found in smoke generated during the heating of sucralose and in the residues after heating. CuO enhanced the PCDD/F yield in comparison with Al2O3 and Fe2O3.
引用
收藏
页数:4
相关论文
共 50 条
  • [21] Evaluation of the Spanish hot dip galvanising sector as a source of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans
    Martinez, M. Angeles
    Sanz, Paloina
    Ruiz, M. Luisa
    Fabrellas, Begona
    Abad, Esteban
    Rivera, Josep
    CHEMOSPHERE, 2008, 71 (06) : 1127 - 1134
  • [22] Levels of polychlorinated dibenzo-p-dioxins and dibenzofurans in mountainous and park soils in Beijing, China
    Li, Wei
    Li, Chaoqin
    Chen, Zuosheng
    Ding, Naixiu
    Cai, Zongwei
    INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2014, 94 (07) : 691 - 711
  • [23] Advances in analytical techniques for polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans and dioxin-like PCBs
    Eric J. Reiner
    Ray E. Clement
    Allan B. Okey
    Chris H. Marvin
    Analytical and Bioanalytical Chemistry, 2006, 386 : 791 - 806
  • [24] Historical trends of polychlorinated dibenzo-p-dioxins and dibenzofurans in three dated sediment cores from Mexico
    Yunuen, Canedo-Lopez
    Vinicio, Macias-Zamora J.
    Miguel Angel, Huerta-Diaz
    Kwong, Laval Liong Wee
    Albert Sanchez-Cabeza, Joan
    ENVIRONMENTAL POLLUTION, 2011, 159 (02) : 487 - 494
  • [25] The formation of polychlorinated dibenzo-p-dioxins/dibenzofurans from carbon model mixtures containing ferrous chloride
    Ryan, SP
    Altwicker, ER
    CHEMOSPHERE, 2000, 40 (9-11) : 1009 - 1014
  • [26] Polychlorinated diphenyl ethers, dibenzo-p-dioxins, dibenzofurans and biphenyls in seals and sediment from the Gulf of Finland
    Koistinen, J
    Stenman, O
    Haahti, H
    Suonpera, M
    Paasivirta, J
    CHEMOSPHERE, 1997, 35 (06) : 1249 - 1269
  • [27] Emission Characteristics and Formation Pathways of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans from a Typical Pesticide Plant
    Ma, Yufeng
    Lin, Xiaoqing
    Chen, Zhiliang
    Chen, Tong
    Zhan, Mingxiu
    Xu, Shuaixi
    Wu, Hailong
    Li, Xiaodong
    Yan, Jianhua
    AEROSOL AND AIR QUALITY RESEARCH, 2019, 19 (06) : 1390 - 1399
  • [28] Formation and potential mechanisms of polychlorinated dibenzo-p-dioxins and dibenzofurans on fly ash from a secondary copper smelting process
    Wang, Mei
    Liu, Guorui
    Jiang, Xiaoxu
    Xiao, Ke
    Zheng, Minghui
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2015, 22 (11) : 8747 - 8755
  • [29] Mechanisms for formation, chlorination, dechlorination and destruction of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs)
    Altarawneh, Mohammednoor
    Dlugogorski, Bogdan Z.
    Kennedy, Eric M.
    Mackie, John C.
    PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2009, 35 (03) : 245 - 274
  • [30] Polychlorinated biphenyl congeners as markers of toxic equivalents of polychlorinated biphenyls, dibenzo-p-dioxins and dibenzofurans in breast milk
    Glynn, AW
    Atuma, S
    Aune, M
    Darnerud, PO
    Cnattingius, S
    ENVIRONMENTAL RESEARCH, 2001, 86 (03) : 217 - 228